DICP OpenIR
Cross-linked beta alumina nanowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery
Lei, Danni1,2; He, Yan-Bing1; Huang, Huijuan3; Yuan, Yifei4; Zhong, Guiming5; Zhao, Qiang1; Hao, Xiaoge1; Zhang, Danfeng1; Lai, Chen6; Zhang, Siwei7; Ma, Jiabin1; Wei, Yinping1; Yu, Qipeng1; Lv, Wei1; Yu, Yan3,8; Li, Baohua1; Yang, Quan-Hong9; Yang, Yong10; Lu, Jun4; Kang, Feiyu1,7
Corresponding AuthorHe, Yan-Bing(he.yanbing@sz.tsinghua.edu.cn) ; Yu, Yan() ; Lu, Jun(junlu@anl.gov) ; Kang, Feiyu(fykang@sz.tsinghua.edu.cn)
Source PublicationNATURE COMMUNICATIONS
2019-09-18
ISSN2041-1723
DOI10.1038/s41467-019-11960-w
Volume10Pages:11
Funding ProjectNational Key Research Program[2018YFB0905400] ; National Natural Science Foundation of China[51672156] ; National Natural Science Foundation of China[51622210] ; National Natural Science Foundation of China[51872277] ; National Natural Science Foundation of China[51802361] ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N111] ; Guangdong special support program[2015TQ01N401] ; Guangdong Province Technical Plan Project[2017B010119001] ; Guangdong Province Technical Plan Project[2017B090907005] ; Shenzhen Technical Plan Project[JCYJ20170412170706047] ; Shenzhen Technical Plan Project[JCYJ20170307153806471] ; Shenzhen Technical Plan Project[JCYJ20170817161221958] ; DNL cooperation Fund, CAS[DNL180310] ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; DOE Office of Science[DE-AC02-06CH11357]
Funding OrganizationNational Key Research Program ; National Key Research Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Guangdong special support program ; Guangdong special support program ; Guangdong Province Technical Plan Project ; Guangdong Province Technical Plan Project ; Shenzhen Technical Plan Project ; Shenzhen Technical Plan Project ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; DOE Office of Science ; DOE Office of Science ; National Key Research Program ; National Key Research Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Guangdong special support program ; Guangdong special support program ; Guangdong Province Technical Plan Project ; Guangdong Province Technical Plan Project ; Shenzhen Technical Plan Project ; Shenzhen Technical Plan Project ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; DOE Office of Science ; DOE Office of Science ; National Key Research Program ; National Key Research Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Guangdong special support program ; Guangdong special support program ; Guangdong Province Technical Plan Project ; Guangdong Province Technical Plan Project ; Shenzhen Technical Plan Project ; Shenzhen Technical Plan Project ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; DOE Office of Science ; DOE Office of Science ; National Key Research Program ; National Key Research Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Guangdong special support program ; Guangdong special support program ; Guangdong Province Technical Plan Project ; Guangdong Province Technical Plan Project ; Shenzhen Technical Plan Project ; Shenzhen Technical Plan Project ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; DOE Office of Science ; DOE Office of Science
WOS SubjectMultidisciplinary Sciences
WOS Research AreaScience & Technology - Other Topics
WOS KeywordION-TRANSPORT ; ENERGY ; INTERPHASES ; CHALLENGES ; STABILITY ; NA
AbstractSodium metal batteries have potentially high energy densities, but severe sodium-dendrite growth and side reactions prevent their practical applications, especially at high temperatures. Herein, we design an inorganic ionic conductor/gel polymer electrolyte composite, where uniformly cross-linked beta alumina nanowires are compactly coated by a poly (vinylidene fluoride-co-hexafluoropropylene)-based gel polymer electrolyte through their strong molecular interactions. These beta alumina nanowires combined with the gel polymer layer create dense and homogeneous solid-liquid hybrid sodium-ion transportation channels through and along the nanowires, which promote uniform sodium deposition and formation of a stable and flat solid electrolyte interface on the sodium metal anode. Side reactions between the sodium metal and liquid electrolyte, as well as sodium dendrite formation, are successfully suppressed, especially at 60 degrees C. The sodium vanadium phosphate/sodium full cells with composite electrolyte exhibit 95.3% and 78.8% capacity retention after 1000 cycles at 1C at 25 degrees C and 60 degrees C, respectively.
Language英语
Funding OrganizationNational Key Research Program ; National Key Research Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Guangdong special support program ; Guangdong special support program ; Guangdong Province Technical Plan Project ; Guangdong Province Technical Plan Project ; Shenzhen Technical Plan Project ; Shenzhen Technical Plan Project ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; DOE Office of Science ; DOE Office of Science ; National Key Research Program ; National Key Research Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Guangdong special support program ; Guangdong special support program ; Guangdong Province Technical Plan Project ; Guangdong Province Technical Plan Project ; Shenzhen Technical Plan Project ; Shenzhen Technical Plan Project ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; DOE Office of Science ; DOE Office of Science ; National Key Research Program ; National Key Research Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Guangdong special support program ; Guangdong special support program ; Guangdong Province Technical Plan Project ; Guangdong Province Technical Plan Project ; Shenzhen Technical Plan Project ; Shenzhen Technical Plan Project ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; DOE Office of Science ; DOE Office of Science ; National Key Research Program ; National Key Research Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Local Innovative Research Teams Project of Guangdong Pearl River Talents Program ; Guangdong special support program ; Guangdong special support program ; Guangdong Province Technical Plan Project ; Guangdong Province Technical Plan Project ; Shenzhen Technical Plan Project ; Shenzhen Technical Plan Project ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office ; DOE Office of Science ; DOE Office of Science
WOS IDWOS:000486374800006
PublisherNATURE PUBLISHING GROUP
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/172793
Collection中国科学院大连化学物理研究所
Corresponding AuthorHe, Yan-Bing; Yu, Yan; Lu, Jun; Kang, Feiyu
Affiliation1.Tsinghua Univ, Shenzhen Geim Graphene Ctr, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China
2.Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, Sch Mat Sci & Engn, Guangzhou 510275, Guangdong, Peoples R China
3.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Dept Mat Sci & Engn, Key Lab Mat Energy Convers,CAS, Hefei 230026, Anhui, Peoples R China
4.Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA
5.Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen 361024, Fujian, Peoples R China
6.Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Shaanxi, Peoples R China
7.Tsinghua Univ, Shenzhen Environm Sci & New Energy Technol Engn L, TBSI, Shenzhen 518055, Peoples R China
8.Chinese Acad Sci, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Liaoning, Peoples R China
9.Tianjin Univ, Sch Chem Engn & Technol, Nanoyang Grp, Tianjin 300072, Peoples R China
10.Xiamen Univ, State Key Lab Phys Chem Solid Surface, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Fujian, Peoples R China
Recommended Citation
GB/T 7714
Lei, Danni,He, Yan-Bing,Huang, Huijuan,et al. Cross-linked beta alumina nanowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery[J]. NATURE COMMUNICATIONS,2019,10:11.
APA Lei, Danni.,He, Yan-Bing.,Huang, Huijuan.,Yuan, Yifei.,Zhong, Guiming.,...&Kang, Feiyu.(2019).Cross-linked beta alumina nanowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery.NATURE COMMUNICATIONS,10,11.
MLA Lei, Danni,et al."Cross-linked beta alumina nanowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery".NATURE COMMUNICATIONS 10(2019):11.
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