DICP OpenIR
Enhanced Hydrogenation Performance over Hollow Structured Co-CoOx@N-C Capsules
Tian, Hao1,2,3; Liu, Xiaoyan1,4; Dong, Liubing3; Ren, Xiaomin1; Liu, Hao3,5; Price, Cameron Alexander Hurd1; Li, Ying4; Wang, Guoxiu3; Yang, Qihua1; Liu, Jian1,2
Corresponding AuthorLiu, Jian(jianliu@dicp.ac.cn)
Keywordconfined catalysis hydrogenation mesoporous materials nanoreactors
Source PublicationADVANCED SCIENCE
2019-09-03
DOI10.1002/advs.201900807
Pages13
Funding ProjectDalian National Laboratory for Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS[DNL180402] ; Australian Research Council LIEF grant[LE120100026] ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government 1000 Young Talent Plan ; ARC[DP180102297] ; ARC[FT180100705]
Funding OrganizationDalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Australian Research Council LIEF grant ; Australian Research Council LIEF grant ; Curtin Strategic International Research Scholarship ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government 1000 Young Talent Plan ; Chinese Government 1000 Young Talent Plan ; ARC ; ARC ; Dalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Australian Research Council LIEF grant ; Australian Research Council LIEF grant ; Curtin Strategic International Research Scholarship ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government 1000 Young Talent Plan ; Chinese Government 1000 Young Talent Plan ; ARC ; ARC ; Dalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Australian Research Council LIEF grant ; Australian Research Council LIEF grant ; Curtin Strategic International Research Scholarship ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government 1000 Young Talent Plan ; Chinese Government 1000 Young Talent Plan ; ARC ; ARC ; Dalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Australian Research Council LIEF grant ; Australian Research Council LIEF grant ; Curtin Strategic International Research Scholarship ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government 1000 Young Talent Plan ; Chinese Government 1000 Young Talent Plan ; ARC ; ARC
WOS SubjectChemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS KeywordMETAL-ORGANIC FRAMEWORKS ; SELECTIVE CATALYTIC-HYDROGENATION ; POROUS CARBON ; NANOPOROUS CARBON ; YOLK-SHELL ; FUNCTIONALIZED NITROARENES ; PD NANOPARTICLES ; NANOSPHERES ; OXYGEN ; DESIGN
AbstractIt is desirable to design nonprecious metal nanocatalysts with high stability and catalytic performance for fine chemicals production. Here, a method is reported for the preparation of cobalt metal and cobalt oxide cores confined within nanoporous nitrogen-doped hollow carbon capsules. Core-shell structured Zn/Co-ZIF@polymer materials are fabricated through a facile coating polymer strategy on the surface of zeolitic imidazolate frameworks (ZIF). A series of hollow carbon capsules with cobalt metal and cobalt oxide are derived from a facile confined pyrolysis of Zn/Co-ZIF@polymer. The hollow Co-CoOx@N-C capsules can prevent sintering and agglomeration of the cobalt nanoparticles and the nanoporous shell allows for efficient mass transport. The specific surface area and Co particle size are optimized through finely tuning the original Zn content in ZIF particles, thus enhancing overall catalytic activity. The yolk-shell structured Zn4Co1Ox@carbon hollow capsules are shown to be a highly active and selective catalyst (selectivity >99%) for hydrogenation of nitrobenzene to aniline. Furthermore, Zn4Co1Ox@carbon hollow particles show superior catalytic stability, and no deactivation after 8 cycles of reaction. The hollow Co-CoOx@N-C capsules may shed light on a green and sustainable catalytic process for fine chemicals production.
Language英语
Funding OrganizationDalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Australian Research Council LIEF grant ; Australian Research Council LIEF grant ; Curtin Strategic International Research Scholarship ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government 1000 Young Talent Plan ; Chinese Government 1000 Young Talent Plan ; ARC ; ARC ; Dalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Australian Research Council LIEF grant ; Australian Research Council LIEF grant ; Curtin Strategic International Research Scholarship ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government 1000 Young Talent Plan ; Chinese Government 1000 Young Talent Plan ; ARC ; ARC ; Dalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Australian Research Council LIEF grant ; Australian Research Council LIEF grant ; Curtin Strategic International Research Scholarship ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government 1000 Young Talent Plan ; Chinese Government 1000 Young Talent Plan ; ARC ; ARC ; Dalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Australian Research Council LIEF grant ; Australian Research Council LIEF grant ; Curtin Strategic International Research Scholarship ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Chinese Government 1000 Young Talent Plan ; Chinese Government 1000 Young Talent Plan ; ARC ; ARC
WOS IDWOS:000484473900001
PublisherWILEY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/173003
Collection中国科学院大连化学物理研究所
Corresponding AuthorLiu, Jian
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Curtin Univ, Dept Chem Engn, Perth, WA 6845, Australia
3.Univ Technol Sydney, Fac Sci, Sch Math & Phys Sci, Ctr Clean Energy Technol, Sydney, NSW 2007, Australia
4.Zhejiang Univ Technol, Inst Ind Catalysis, 18 Hangzhou Chaowang Rd, Hangzhou, Zhejiang, Peoples R China
5.Shanghai Univ, Sch Environm & Chem Engn, Joint Int Lab Environm & Energy Frontier Mat, Shanghai 200444, Peoples R China
Recommended Citation
GB/T 7714
Tian, Hao,Liu, Xiaoyan,Dong, Liubing,et al. Enhanced Hydrogenation Performance over Hollow Structured Co-CoOx@N-C Capsules[J]. ADVANCED SCIENCE,2019:13.
APA Tian, Hao.,Liu, Xiaoyan.,Dong, Liubing.,Ren, Xiaomin.,Liu, Hao.,...&Liu, Jian.(2019).Enhanced Hydrogenation Performance over Hollow Structured Co-CoOx@N-C Capsules.ADVANCED SCIENCE,13.
MLA Tian, Hao,et al."Enhanced Hydrogenation Performance over Hollow Structured Co-CoOx@N-C Capsules".ADVANCED SCIENCE (2019):13.
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