DICP OpenIR
Construction of a sp(3)/sp(2) Carbon Interface in 3D N-Doped Nanocarbons for the Oxygen Reduction Reaction
Gao, Jian1,2,3,4,11; Wang, Yun5; Wu, Haihua6; Liu, Xi7; Wang, Leilei1; Yu, Qiaolin2,3,4; Li, Aowen8; Wang, Hong1,9; Song, Chuqiao2,3,4; Gao, Zirui2,3,4; Peng, Mi2,3,4; Zhang, Mengtao2,3,4; Ma, Na9; Wang, Jiaou10; Zhou, Wu8; Wang, Guoxiong6; Yin, Zhen1,11; Ma, Ding2,3,4
Corresponding AuthorYin, Zhen(yinzhen@tjpu.edu.cn) ; Ma, Ding(dma@pku.edu.cn)
Keywordelectrocatalysis metal-air batteries metal-free electrocatalysts oxygen reduction reaction porous carbon
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2019-09-18
ISSN1433-7851
DOI10.1002/anie.201907915
Pages10
Funding ProjectNational Natural Science Foundation of China[21872104] ; National Natural Science Foundation of China[21932002] ; National Natural Science Foundation of China[21821004] ; National Natural Science Foundation of China[21776219] ; National Natural Science Foundation of China[21725301] ; National Natural Science Foundation of China[91645115] ; National Natural Science Foundation of China[21673273] ; National Natural Science Foundation of China[21872163] ; National Key R&D Program of China[2017YFB0602200] ; Australian Commonwealth Government ; Australian government ; Government of Western Australia ; China Postdoctoral Science Foundation[2018M631746]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key R&D Program of China ; National Key R&D Program of China ; Australian Commonwealth Government ; Australian Commonwealth Government ; Australian government ; Australian government ; Government of Western Australia ; Government of Western Australia ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key R&D Program of China ; National Key R&D Program of China ; Australian Commonwealth Government ; Australian Commonwealth Government ; Australian government ; Australian government ; Government of Western Australia ; Government of Western Australia ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key R&D Program of China ; National Key R&D Program of China ; Australian Commonwealth Government ; Australian Commonwealth Government ; Australian government ; Australian government ; Government of Western Australia ; Government of Western Australia ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key R&D Program of China ; National Key R&D Program of China ; Australian Commonwealth Government ; Australian Commonwealth Government ; Australian government ; Australian government ; Government of Western Australia ; Government of Western Australia ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordDIAMOND-LIKE-CARBON ; METAL-FREE ELECTROCATALYSTS ; BIFUNCTIONAL CATALYSTS ; IONIC LIQUIDS ; SURFACE-AREA ; ACTIVE-SITES ; GRAPHENE ; FILMS ; GRAPHDIYNE ; NANOMATERIALS
AbstractThe development of highly efficient metal-free carbon electrocatalysts for the oxygen reduction reaction (ORR) is one very promising strategy for the exploitation and commercialization of renewable and clean energy, but this still remains a significant challenge. Herein, we demonstrate a facile approach to prepare three-dimensional (3D) N-doped carbon with a sp(3)/sp(2) carbon interface derived from ionic liquids via a simple pyrolysis process. The tunable hybrid sp(3) and sp(2) carbon composition and pore structures stem from the transformation of ionic liquids to polymerized organics and introduction of a Co metal salt. Through tuning both composition and pores, the 3D N-doped nanocarbon with a high sp(3)/sp(2) carbon ratio on the surface exhibits a superior electrocatalytic performance for the ORR compared to that of the commercial Pt/C in Zn-air batteries. Density functional theory calculations suggest that the improved ORR performance can be ascribed to the existence of N dopants at the sp(3)/sp(2) carbon interface, which can lower the theoretical overpotential of the ORR.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key R&D Program of China ; National Key R&D Program of China ; Australian Commonwealth Government ; Australian Commonwealth Government ; Australian government ; Australian government ; Government of Western Australia ; Government of Western Australia ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key R&D Program of China ; National Key R&D Program of China ; Australian Commonwealth Government ; Australian Commonwealth Government ; Australian government ; Australian government ; Government of Western Australia ; Government of Western Australia ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key R&D Program of China ; National Key R&D Program of China ; Australian Commonwealth Government ; Australian Commonwealth Government ; Australian government ; Australian government ; Government of Western Australia ; Government of Western Australia ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key R&D Program of China ; National Key R&D Program of China ; Australian Commonwealth Government ; Australian Commonwealth Government ; Australian government ; Australian government ; Government of Western Australia ; Government of Western Australia ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation
WOS IDWOS:000486812500001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/173078
Collection中国科学院大连化学物理研究所
Corresponding AuthorYin, Zhen; Ma, Ding
Affiliation1.Tianjin Polytech Univ, Dept Chem Engn, State Key Lab Separat Membranes & Membrane Proc, 399 Binshui West Rd, Tianjin 300387, Peoples R China
2.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
3.Peking Univ, Coll Engn, Beijing 100871, Peoples R China
4.Peking Univ, BIC ESAT, Beijing 100871, Peoples R China
5.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Nathan, Qld 4222, Australia
6.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Ctr Excellence Nanosci, State Key Lab Catalysis, Dalian 116023, Peoples R China
7.Synfuels China Technol Co Ltd, SynCat Beijing, Beijing 101407, Peoples R China
8.Univ Chinese Acad Sci, CAS Key Lab Vacuum Phys, Sch Phys Sci, Beijing 100049, Peoples R China
9.Tianjin Polytech Univ, Sch Mat Sci & Engn, Tianjin 300387, Peoples R China
10.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China
11.Tianjin Polytech Univ, Tianjin Key Lab Green Chem Technol & Proc Engn, Tianjin 300387, Peoples R China
Recommended Citation
GB/T 7714
Gao, Jian,Wang, Yun,Wu, Haihua,et al. Construction of a sp(3)/sp(2) Carbon Interface in 3D N-Doped Nanocarbons for the Oxygen Reduction Reaction[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019:10.
APA Gao, Jian.,Wang, Yun.,Wu, Haihua.,Liu, Xi.,Wang, Leilei.,...&Ma, Ding.(2019).Construction of a sp(3)/sp(2) Carbon Interface in 3D N-Doped Nanocarbons for the Oxygen Reduction Reaction.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,10.
MLA Gao, Jian,et al."Construction of a sp(3)/sp(2) Carbon Interface in 3D N-Doped Nanocarbons for the Oxygen Reduction Reaction".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019):10.
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