DICP OpenIR
Encapsulating a Ni(II) molecular catalyst in photoactive metal-organic framework for highly efficient photoreduction of CO2
Yan, Zhi-Hao1,2; Ma, Bo1,2; Li, Shu-Rong1,2; Liu, Junxue3,4; Chen, Rong1,2; Du, Ming-Hao1,2; Jin, Shengye3,4; Zhuang, Gui-Lin5; Long, La-Sheng1,2; Kong, Xiang-Jian1,2; Zheng, Lan-Sun1,2
Corresponding AuthorJin, Shengye(sjin@dicp.ac.cn) ; Kong, Xiang-Jian(xjkong@xinu.edu.cn)
KeywordMetal-organic frameworks CO2 reduction Transient absorption Photocatalysis DFT calculations
Source PublicationSCIENCE BULLETIN
2019-07-30
ISSN2095-9273
DOI10.1016/j.scib.2019.05.014
Volume64Issue:14Pages:976-985
Funding ProjectNational Natural Science Foundation of China[21871224] ; National Natural Science Foundation of China[21673184] ; National Natural Science Foundation of China[21431005] ; National Natural Science Foundation of China[21390391] ; Fok Ying Tong Education Foundation[151013] ; Fundamental Research Funds for the Central Universities[20720180032]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying Tong Education Foundation ; Fok Ying Tong Education Foundation ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying Tong Education Foundation ; Fok Ying Tong Education Foundation ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying Tong Education Foundation ; Fok Ying Tong Education Foundation ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying Tong Education Foundation ; Fok Ying Tong Education Foundation ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities
WOS SubjectMultidisciplinary Sciences
WOS Research AreaScience & Technology - Other Topics
WOS KeywordPHOTOCATALYTIC REDUCTION ; CARBON-DIOXIDE ; LIGHT ; DRIVEN ; NANOPARTICLES ; NICKEL(II) ; COMPLEXES ; SPECTRA ; SYSTEMS ; TIO2
AbstractPhotocatalytic reduction of CO2 to CO is a promising strategy for reducing atmospheric CO2 levels and storing solar radiation as chemical energy. Here, we demonstrate that a molecular catalyst [Ni-II(bpet) (H2O)(2)] successfully encapsulated into a highly robust and visible-light responsive metal-organic framework (Ru-UiO-67) to fabricate composite catalysts for photocatalytic CO2 reduction. The composite Ni@Ru-UiO-67 photocatalysts show efficient visible-light-driven CO2 reduction to CO with a TON of 581 and a selectivity of 99% after 20-h illumination, because of the facile electron transfer from Ru-photosensitizer to Ni(II) active sites in Ni@Ru-UiO-67 system. The mechanistic insights into photoreduction of CO2 have been studied based on thermodynamical, electrochemical, and spectroscopic investigation, together with density functional theory (DFT) calculations. This work shows that encapsulating molecular catalyst into photoactive MOF highlights opportunities for designing efficient, stable and recyclable photocatalysts. (C) 2019 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying Tong Education Foundation ; Fok Ying Tong Education Foundation ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying Tong Education Foundation ; Fok Ying Tong Education Foundation ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying Tong Education Foundation ; Fok Ying Tong Education Foundation ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying Tong Education Foundation ; Fok Ying Tong Education Foundation ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities
WOS IDWOS:000483302400007
PublisherELSEVIER
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/173285
Collection中国科学院大连化学物理研究所
Corresponding AuthorJin, Shengye; Kong, Xiang-Jian
Affiliation1.Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Fujian, Peoples R China
2.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Fujian, Peoples R China
3.Chinese Acad Sci, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
4.Chinese Acad Sci, Collaborat Innovat Ctr Chem Energy Mat, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
5.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Zhejiang, Peoples R China
Recommended Citation
GB/T 7714
Yan, Zhi-Hao,Ma, Bo,Li, Shu-Rong,et al. Encapsulating a Ni(II) molecular catalyst in photoactive metal-organic framework for highly efficient photoreduction of CO2[J]. SCIENCE BULLETIN,2019,64(14):976-985.
APA Yan, Zhi-Hao.,Ma, Bo.,Li, Shu-Rong.,Liu, Junxue.,Chen, Rong.,...&Zheng, Lan-Sun.(2019).Encapsulating a Ni(II) molecular catalyst in photoactive metal-organic framework for highly efficient photoreduction of CO2.SCIENCE BULLETIN,64(14),976-985.
MLA Yan, Zhi-Hao,et al."Encapsulating a Ni(II) molecular catalyst in photoactive metal-organic framework for highly efficient photoreduction of CO2".SCIENCE BULLETIN 64.14(2019):976-985.
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