DICP OpenIR
Breaking the Limit of Lignin Monomer Production via Cleavage of Interunit Carbon-Carbon Linkages
Dong, Lin1,2; Lin, Longfei3; Han, Xue3; Si, Xiaoqin4; Liu, Xiaohui1,2; Guo, Yong1,2; Lu, Fang4; Rudic, Svemir5; Parker, Stewart F.5; Yang, Sihai3; Wang, Yanqin1,2
Corresponding AuthorGuo, Yong(guoyong@ecust.edu.cn) ; Yang, Sihai(sihai.yang@manchester.ac.uk) ; Wang, Yanqin(wangyanqin@ecust.edu.cn)
Source PublicationCHEM
2019-06-13
ISSN2451-9294
DOI10.1016/j.chempr.2019.03.007
Volume5Issue:6Pages:1521-1536
Funding ProjectNational Natural Science Foundation of China[21832002] ; National Natural Science Foundation of China[21872050] ; National Natural Science Foundation of China[21808063] ; National Natural Science Foundation of China[91545103] ; Science and Technology Commission of Shanghai Municipality[2018SHZDZX03] ; Programme of Introducing Talents of Discipline to Universities in China[B16017] ; Fundamental Research Funds for the Central Universities[222201718003] ; University of Manchester ; Royal Society ; Engineering and Physical Sciences Research Council in the UK[EP/P011632/1]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; Programme of Introducing Talents of Discipline to Universities in China ; Programme of Introducing Talents of Discipline to Universities in China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; University of Manchester ; University of Manchester ; Royal Society ; Royal Society ; Engineering and Physical Sciences Research Council in the UK ; Engineering and Physical Sciences Research Council in the UK ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; Programme of Introducing Talents of Discipline to Universities in China ; Programme of Introducing Talents of Discipline to Universities in China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; University of Manchester ; University of Manchester ; Royal Society ; Royal Society ; Engineering and Physical Sciences Research Council in the UK ; Engineering and Physical Sciences Research Council in the UK ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; Programme of Introducing Talents of Discipline to Universities in China ; Programme of Introducing Talents of Discipline to Universities in China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; University of Manchester ; University of Manchester ; Royal Society ; Royal Society ; Engineering and Physical Sciences Research Council in the UK ; Engineering and Physical Sciences Research Council in the UK ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; Programme of Introducing Talents of Discipline to Universities in China ; Programme of Introducing Talents of Discipline to Universities in China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; University of Manchester ; University of Manchester ; Royal Society ; Royal Society ; Engineering and Physical Sciences Research Council in the UK ; Engineering and Physical Sciences Research Council in the UK
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordLIGNOCELLULOSE FRACTIONATION ; DEPOLYMERIZATION ; CONVERSION ; CHEMICALS ; CATALYSTS ; HYDROGENOLYSIS ; AROMATICS ; BIOMASS ; VALORIZATION ; SELECTIVITY
AbstractConversion of lignin into monocyclic hydrocarbons as commodity chemicals and drop-in fuels is a highly desirable target for biorefineries. However, this is severely hindered by the presence of stable interunit carbon-carbon linkages in native lignin and those formed during lignin extraction. Herein, we report a newmultifunctional catalyst, Ru/NbOPO4, that achieves the first example of catalytic cleavage of both interunit C-C and C-O bonds in one-pot lignin conversions to yield 124%-153% of monocyclic hydrocarbons, which is 1.2-1.5 times the yields obtained from the established nitrobenzene oxidation method. This catalyst also exhibits high stability and selectivity (up to 68%) to monocyclic arenes over repeated cycles. The mechanism of the activation and cleavage of 5-5 C-C bonds in biphenyl, as a lignin model adopting the most robust C-C linkages, has been revealed via in situ inelastic neutron scattering coupled with modeling. This study breaks the conventional theoretical limit on lignin monomer production.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; Programme of Introducing Talents of Discipline to Universities in China ; Programme of Introducing Talents of Discipline to Universities in China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; University of Manchester ; University of Manchester ; Royal Society ; Royal Society ; Engineering and Physical Sciences Research Council in the UK ; Engineering and Physical Sciences Research Council in the UK ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; Programme of Introducing Talents of Discipline to Universities in China ; Programme of Introducing Talents of Discipline to Universities in China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; University of Manchester ; University of Manchester ; Royal Society ; Royal Society ; Engineering and Physical Sciences Research Council in the UK ; Engineering and Physical Sciences Research Council in the UK ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; Programme of Introducing Talents of Discipline to Universities in China ; Programme of Introducing Talents of Discipline to Universities in China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; University of Manchester ; University of Manchester ; Royal Society ; Royal Society ; Engineering and Physical Sciences Research Council in the UK ; Engineering and Physical Sciences Research Council in the UK ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; Programme of Introducing Talents of Discipline to Universities in China ; Programme of Introducing Talents of Discipline to Universities in China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; University of Manchester ; University of Manchester ; Royal Society ; Royal Society ; Engineering and Physical Sciences Research Council in the UK ; Engineering and Physical Sciences Research Council in the UK
WOS IDWOS:000476610100013
PublisherCELL PRESS
Citation statistics
Cited Times:17[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/173672
Collection中国科学院大连化学物理研究所
Corresponding AuthorGuo, Yong; Yang, Sihai; Wang, Yanqin
Affiliation1.East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Key Lab Adv Mat,Res Inst Ind Catalysis, Shanghai 200237, Peoples R China
2.East China Univ Sci & Technol, Joint Int Res Lab Precis Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Res Inst Ind Catalysis,Sch Chem & Mol Engn, Shanghai 200237, Peoples R China
3.Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
4.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
5.STFC Rutherford Appleton Lab, ISIS Facil, Chilton OX11 0QX, Oxon, England
Recommended Citation
GB/T 7714
Dong, Lin,Lin, Longfei,Han, Xue,et al. Breaking the Limit of Lignin Monomer Production via Cleavage of Interunit Carbon-Carbon Linkages[J]. CHEM,2019,5(6):1521-1536.
APA Dong, Lin.,Lin, Longfei.,Han, Xue.,Si, Xiaoqin.,Liu, Xiaohui.,...&Wang, Yanqin.(2019).Breaking the Limit of Lignin Monomer Production via Cleavage of Interunit Carbon-Carbon Linkages.CHEM,5(6),1521-1536.
MLA Dong, Lin,et al."Breaking the Limit of Lignin Monomer Production via Cleavage of Interunit Carbon-Carbon Linkages".CHEM 5.6(2019):1521-1536.
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