DICP OpenIR
Diffusion-Limited Formation of Nonequilibrium Intermetallic Nanophase for Selective Dehydrogenation
Zhang, Guanghui1,3; Ye, Chenliang2,3; Liu, Wei4; Zhang, Xiaoben4; Su, Dangsheng4; Yang, Xin3,5; Chen, Johnny Zhu3; Wu, Zhenwei3,6; Miller, Jeffrey T.3
Corresponding AuthorWu, Zhenwei(zhenweiwu@stanford.edu) ; Miller, Jeffrey T.(mill1194@purdue.edu)
KeywordNonequilibrium phase intermetallic compounds diffusion controlled light alkane dehydrogenation
Source PublicationNANO LETTERS
2019-07-01
ISSN1530-6984
DOI10.1021/acs.nanolett.9b00994
Volume19Issue:7Pages:4380-4383
Funding ProjectNational Science Foundation[EEC-1647722] ; Chinese Scholarship Council (CSC) ; Fundamental Research Funds for Central Universities[DUT18RC(3)057] ; Davidson School of Chemical Engineering, Purdue University ; Talents Innovation Project of Dalian[2016RD04] ; CAS Youth Innovation Promotion Association[2019190] ; U.S. Department of Energy, Office of Basic Energy Sciences[DE-AC02-06CH11357] ; Department of Energy
Funding OrganizationNational Science Foundation ; National Science Foundation ; Chinese Scholarship Council (CSC) ; Chinese Scholarship Council (CSC) ; Fundamental Research Funds for Central Universities ; Fundamental Research Funds for Central Universities ; Davidson School of Chemical Engineering, Purdue University ; Davidson School of Chemical Engineering, Purdue University ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; CAS Youth Innovation Promotion Association ; CAS Youth Innovation Promotion Association ; U.S. Department of Energy, Office of Basic Energy Sciences ; U.S. Department of Energy, Office of Basic Energy Sciences ; Department of Energy ; Department of Energy ; National Science Foundation ; National Science Foundation ; Chinese Scholarship Council (CSC) ; Chinese Scholarship Council (CSC) ; Fundamental Research Funds for Central Universities ; Fundamental Research Funds for Central Universities ; Davidson School of Chemical Engineering, Purdue University ; Davidson School of Chemical Engineering, Purdue University ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; CAS Youth Innovation Promotion Association ; CAS Youth Innovation Promotion Association ; U.S. Department of Energy, Office of Basic Energy Sciences ; U.S. Department of Energy, Office of Basic Energy Sciences ; Department of Energy ; Department of Energy ; National Science Foundation ; National Science Foundation ; Chinese Scholarship Council (CSC) ; Chinese Scholarship Council (CSC) ; Fundamental Research Funds for Central Universities ; Fundamental Research Funds for Central Universities ; Davidson School of Chemical Engineering, Purdue University ; Davidson School of Chemical Engineering, Purdue University ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; CAS Youth Innovation Promotion Association ; CAS Youth Innovation Promotion Association ; U.S. Department of Energy, Office of Basic Energy Sciences ; U.S. Department of Energy, Office of Basic Energy Sciences ; Department of Energy ; Department of Energy ; National Science Foundation ; National Science Foundation ; Chinese Scholarship Council (CSC) ; Chinese Scholarship Council (CSC) ; Fundamental Research Funds for Central Universities ; Fundamental Research Funds for Central Universities ; Davidson School of Chemical Engineering, Purdue University ; Davidson School of Chemical Engineering, Purdue University ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; CAS Youth Innovation Promotion Association ; CAS Youth Innovation Promotion Association ; U.S. Department of Energy, Office of Basic Energy Sciences ; U.S. Department of Energy, Office of Basic Energy Sciences ; Department of Energy ; Department of Energy
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS KeywordCATALYSTS ; ALLOY ; NANOPARTICLES ; ZN
AbstractNonequilibrium intermetallic phases in the nanoscale were realized by diffusion-controlled solid-state transformation, forming SiO2 supported NPs with Pd core and a CsCl type Pd1M1 shell, where M is Sn or Sb. The core-shell geometry is identified from scanning transmission electron microscopy and infrared spectroscopy and the crystal structure is confirmed from in situ synchrotron X-ray diffraction and X-ray absorption spectroscopy. The highly symmetric Pd1M1 intermetallic phase has not been reported previously and contains catalytic ensembles with high selectivity toward dehydrogenation of propane. The kinetically limited solid-state reaction is generally applicable to nanoparticle synthesis and could produce materials with desired structures and properties beyond conventional structural limits
Language英语
Funding OrganizationNational Science Foundation ; National Science Foundation ; Chinese Scholarship Council (CSC) ; Chinese Scholarship Council (CSC) ; Fundamental Research Funds for Central Universities ; Fundamental Research Funds for Central Universities ; Davidson School of Chemical Engineering, Purdue University ; Davidson School of Chemical Engineering, Purdue University ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; CAS Youth Innovation Promotion Association ; CAS Youth Innovation Promotion Association ; U.S. Department of Energy, Office of Basic Energy Sciences ; U.S. Department of Energy, Office of Basic Energy Sciences ; Department of Energy ; Department of Energy ; National Science Foundation ; National Science Foundation ; Chinese Scholarship Council (CSC) ; Chinese Scholarship Council (CSC) ; Fundamental Research Funds for Central Universities ; Fundamental Research Funds for Central Universities ; Davidson School of Chemical Engineering, Purdue University ; Davidson School of Chemical Engineering, Purdue University ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; CAS Youth Innovation Promotion Association ; CAS Youth Innovation Promotion Association ; U.S. Department of Energy, Office of Basic Energy Sciences ; U.S. Department of Energy, Office of Basic Energy Sciences ; Department of Energy ; Department of Energy ; National Science Foundation ; National Science Foundation ; Chinese Scholarship Council (CSC) ; Chinese Scholarship Council (CSC) ; Fundamental Research Funds for Central Universities ; Fundamental Research Funds for Central Universities ; Davidson School of Chemical Engineering, Purdue University ; Davidson School of Chemical Engineering, Purdue University ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; CAS Youth Innovation Promotion Association ; CAS Youth Innovation Promotion Association ; U.S. Department of Energy, Office of Basic Energy Sciences ; U.S. Department of Energy, Office of Basic Energy Sciences ; Department of Energy ; Department of Energy ; National Science Foundation ; National Science Foundation ; Chinese Scholarship Council (CSC) ; Chinese Scholarship Council (CSC) ; Fundamental Research Funds for Central Universities ; Fundamental Research Funds for Central Universities ; Davidson School of Chemical Engineering, Purdue University ; Davidson School of Chemical Engineering, Purdue University ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; CAS Youth Innovation Promotion Association ; CAS Youth Innovation Promotion Association ; U.S. Department of Energy, Office of Basic Energy Sciences ; U.S. Department of Energy, Office of Basic Energy Sciences ; Department of Energy ; Department of Energy
WOS IDWOS:000475533900021
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/173834
Collection中国科学院大连化学物理研究所
Corresponding AuthorWu, Zhenwei; Miller, Jeffrey T.
Affiliation1.Dalian Univ Technol, PSU DUT Joint Ctr Energy Res Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China
2.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 30072, Peoples R China
3.Purdue Univ, Davidson Sch Chem Engn, W Lafayette, IN 47907 USA
4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
5.Huaqiao Univ, Sch Chem Engn, Xiamen 361021, Fujian, Peoples R China
6.Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA
Recommended Citation
GB/T 7714
Zhang, Guanghui,Ye, Chenliang,Liu, Wei,et al. Diffusion-Limited Formation of Nonequilibrium Intermetallic Nanophase for Selective Dehydrogenation[J]. NANO LETTERS,2019,19(7):4380-4383.
APA Zhang, Guanghui.,Ye, Chenliang.,Liu, Wei.,Zhang, Xiaoben.,Su, Dangsheng.,...&Miller, Jeffrey T..(2019).Diffusion-Limited Formation of Nonequilibrium Intermetallic Nanophase for Selective Dehydrogenation.NANO LETTERS,19(7),4380-4383.
MLA Zhang, Guanghui,et al."Diffusion-Limited Formation of Nonequilibrium Intermetallic Nanophase for Selective Dehydrogenation".NANO LETTERS 19.7(2019):4380-4383.
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