DICP OpenIR
Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters
Ma, Yangyang1,2; Ma, Jiping1; Xia, Fei1; Lu, Fang1; Du, Zhongtian1; Xu, Jie1
Corresponding AuthorMa, Jiping(majiping@dicp.ac.cn) ; Xu, Jie(xujie@dicp.ac.cn)
Keywordoxidation oxygen molybdenum mono-aromatics acid esters
Source PublicationASIAN JOURNAL OF ORGANIC CHEMISTRY
2019-07-10
ISSN2193-5807
DOI10.1002/ajoc.201900310
Pages7
Funding ProjectNational Natural Science Foundation of China[21790331] ; National Natural Science Foundation of China[21473184] ; National Natural Science Foundation of China[30900326] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17020300] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA21030400] ; Youth Innovation Promotion Association, CAS[2018219] ; DICP[ZZBS201811]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordLIGNOCELLULOSIC BIOMASS ; WOODY BIOMASS ; FORMIC-ACID ; LIGNIN ; CONVERSION ; CHEMICALS ; DEPOLYMERIZATION ; CELLULOSE ; NICKEL ; HYDROGENOLYSIS
AbstractConversion of non-edible lignocellulosic biomass into value-added chemicals is of great significance and also particularly attractive. However, owing to the complexity and inertness, valorization of native lignocellulose remains to be quite challenging. Herein, catalytic oxidative cleavage of raw poplar sawdust was studied, mono-aromatics and organic acid esters with 34.8 wt% and 27.4 wt% yield respectively were achieved over MoO2(acac)(2) with molecular oxygen, which was suggested to be attributed to a prior cleavage of the carbohydrate fractions. This catalytic oxidation approach demonstrates the feasibility of transformation of raw woody biomass into valuable chemicals.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP
WOS IDWOS:000477467000001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/173879
Collection中国科学院大连化学物理研究所
Corresponding AuthorMa, Jiping; Xu, Jie
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Henan Agr Univ, Coll Food Sci & Technol, Zhengzhou 450002, Henan, Peoples R China
Recommended Citation
GB/T 7714
Ma, Yangyang,Ma, Jiping,Xia, Fei,et al. Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2019:7.
APA Ma, Yangyang,Ma, Jiping,Xia, Fei,Lu, Fang,Du, Zhongtian,&Xu, Jie.(2019).Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters.ASIAN JOURNAL OF ORGANIC CHEMISTRY,7.
MLA Ma, Yangyang,et al."Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters".ASIAN JOURNAL OF ORGANIC CHEMISTRY (2019):7.
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