DICP OpenIR
Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans
Luo, Nengchao1,2; Montini, Tiziano3; Zhang, Jian1; Fornasiero, Paolo3; Fonda, Emiliano4; Hou, Tingting1,2; Nie, Wei1,2; Lu, Jianmin1; Liu, Junxue5,6; Heggen, Marc7,8; Lin, Long1,2; Ma, Changtong1,2; Wang, Min1; Fan, Fengtao1; Jin, Shengye5,6; Wang, Feng1
Corresponding AuthorWang, Feng(wangfeng@dicp.ac.cn)
Source PublicationNATURE ENERGY
2019-07-01
ISSN2058-7546
DOI10.1038/s41560-019-0403-5
Volume4Issue:7Pages:575-584
Funding ProjectNational Natural Science Foundation of China[21721004] ; National Natural Science Foundation of China[21690082] ; National Natural Science Foundation of China[21690084] ; National Natural Science Foundation of China[21690080] ; National Natural Science Foundation of China[21711530020] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17020300] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17000000] ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium
WOS SubjectEnergy & Fuels ; Materials Science, Multidisciplinary
WOS Research AreaEnergy & Fuels ; Materials Science
WOS KeywordHIGH-QUALITY DIESEL ; CATALYTIC CONVERSION ; EFFICIENT SYNTHESIS ; LIQUID ALKANES ; LIGNIN MODELS ; PLATFORM ; 2,5-DIMETHYLFURAN ; NANOPARTICLES ; 2-METHYLFURAN ; CHEMICALS
AbstractPhotocatalytic hydrogen production from biomass is a promising alternative to water splitting thanks to the oxidation half-reaction being more facile and its ability to simultaneously produce solar fuels and value-added chemicals. Here, we demonstrate the coproduction of H-2 and diesel fuel precursors from lignocellulose-derived methylfurans via acceptorless dehydrogenative C-C coupling, using a Ru-doped ZnIn2S4 catalyst and driven by visible light. With this chemistry, up to 1.04 g g(catalyst)(-1)h(-1) of diesel fuel precursors (similar to 41% of which are precursors of branched-chain alkanes) are produced with selectivity higher than 96%, together with 6.0 mmol g(catalyst)(-1) h(-1) of H-2. Subsequent hydrodeoxygenation reactions yield the desired diesel fuels comprising straight- and branched-chain alkanes. We suggest that Ru dopants, substituted in the position of indium ions in the ZnIn2S4 matrix, improve charge separation efficiency, thereby accelerating C-H activation for the coproduction of H-2 and diesel fuel precursors.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium
WOS IDWOS:000474920100014
PublisherNATURE PUBLISHING GROUP
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/175175
Collection中国科学院大连化学物理研究所
Corresponding AuthorWang, Feng
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian, Peoples R China
2.Univ Chinese Acad Sci, Beijing, Peoples R China
3.Univ Trieste, Dept Chem & Pharmaceut Sci, INSTM Res Unit, ICCOM CNR Trieste Res Unit, Trieste, Italy
4.Synchrotron SOLEIL, Paris, France
5.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian, Peoples R China
6.Chinese Acad Sci, Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian Inst Chem Phys, Dalian, Peoples R China
7.Forschungszentrum Julich, Ernst Ruska Ctr Microscopy & Spect Electron, Julich, Germany
8.Forschungszentrum Julich, Peter Grunberg Inst, Julich, Germany
Recommended Citation
GB/T 7714
Luo, Nengchao,Montini, Tiziano,Zhang, Jian,et al. Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans[J]. NATURE ENERGY,2019,4(7):575-584.
APA Luo, Nengchao.,Montini, Tiziano.,Zhang, Jian.,Fornasiero, Paolo.,Fonda, Emiliano.,...&Wang, Feng.(2019).Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans.NATURE ENERGY,4(7),575-584.
MLA Luo, Nengchao,et al."Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans".NATURE ENERGY 4.7(2019):575-584.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Luo, Nengchao]'s Articles
[Montini, Tiziano]'s Articles
[Zhang, Jian]'s Articles
Baidu academic
Similar articles in Baidu academic
[Luo, Nengchao]'s Articles
[Montini, Tiziano]'s Articles
[Zhang, Jian]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Luo, Nengchao]'s Articles
[Montini, Tiziano]'s Articles
[Zhang, Jian]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.