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The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins
Yang, Xiaoling1; Bai, Ying1; Li, Jiayun1; Liu, Yu1; Peng, Jiajian1; Li, Tianbo2; Lang, Rui2; Qiao, Botao2
Corresponding AuthorBai, Ying(ybai@hznu.edu.cn) ; Peng, Jiajian(jjpeng@hznu.edu.cn)
KeywordHydrosilylation titanium alkoxide alkali metal alkoxide olefin
Source PublicationPHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
2019
ISSN1042-6507
DOI10.1080/10426507.2018.1493480
Volume194Issue:1-2Pages:83-86
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Organic
WOS Research AreaChemistry
WOS KeywordALKENE HYDROSILYLATION ; COMPLEXES ; IRON ; REDUCTION
AbstractThe catalytic activities of titanium alkoxides and alkali metal alkoxides for hydrosilylation of unfunctionalized olefins have been studied. Titanium(IV) alkoxides showed excellent catalytic activity, while alkali metal alkoxides have low catalytic activity for the hydrosilylation of olefins. However, by using titanocene dichloride as an additive, alkali metal alkoxides showed also excellent catalytic property for hydrosilylation. In comparison with titanium alkoxides, no -adduct was obtained by using alkali metal alkoxides/Cp2TiCl2 as catalysts.
Language英语
WOS IDWOS:000469421300012
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/175875
Collection中国科学院大连化学物理研究所
Corresponding AuthorBai, Ying; Peng, Jiajian
Affiliation1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
Recommended Citation
GB/T 7714
Yang, Xiaoling,Bai, Ying,Li, Jiayun,et al. The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,2019,194(1-2):83-86.
APA Yang, Xiaoling.,Bai, Ying.,Li, Jiayun.,Liu, Yu.,Peng, Jiajian.,...&Qiao, Botao.(2019).The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins.PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,194(1-2),83-86.
MLA Yang, Xiaoling,et al."The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins".PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 194.1-2(2019):83-86.
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