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carbonsupportedultrafineptnanoparticlesmodifiedwithtraceamountsofcobaltasenhancedoxygenreductionreactioncatalystsforprotonexchangemembranefuelcells
Qu Lijuan1; Fang Dahui1; Xu Dongyan3; Qin Xiaoping2; Qin Bowen1; Tang Xuejun1; Song Wei2; Shao Zhigang2; Yi Baolian2
Source Publicationchinesejournalofcatalysis
2019-01-01
ISSN0253-9837
Volume40Issue:4Pages:504
AbstractTo accelerate the kinetics of the oxygen reduction reaction (orr) in proton exchange membrane fuel cells, ultrafine pt nanoparticles modified with trace amounts of cobalt were fabricated and decorated on carbon black through a strategy involving modified glycol reduction and chemical etching. the obtained pt36co/c catalyst exhibits a much larger electrochemical surface area (ecsa) and an improved orr electrocatalytic activity compared to commercial pt/c. moreover, an electrode prepared with pt36co/c was further evaluated under h-2-air single cell test conditions, and exhibited a maximum specific power density of 10.27 w mg(pt)(-1),which is 1.61 times higher than that of a conventional pt/c electrode and also competitive with most state-of-the-art pt -based architectures. in addition, the changes in ecsa, power density, and reacting resistance during the accelerated degradation process further demonstrate the enhanced durability of the pt36co/c electrode. the superior performance observed in this work can be attributed to the synergy between the ultrasmall size and homogeneous distribution of catalyst nanoparticles, bimetallic ligand and electronic effects, and the dissolution of unstable co with the rearrangement of surface structure brought about by acid etching. furthermore, the accessible raw materials and simplified operating procedures involved in the fabrication process would result in great cost-effectiveness for practical applications of pemfcs. (c) 2019, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved.
Language英语
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/177760
Collection中国科学院大连化学物理研究所
Affiliation1.中国科学院研究生院
2.中国科学院大连化学物理研究所
3.黑龙江省环境保护科学研究院
Recommended Citation
GB/T 7714
Qu Lijuan,Fang Dahui,Xu Dongyan,et al. carbonsupportedultrafineptnanoparticlesmodifiedwithtraceamountsofcobaltasenhancedoxygenreductionreactioncatalystsforprotonexchangemembranefuelcells[J]. chinesejournalofcatalysis,2019,40(4):504.
APA Qu Lijuan.,Fang Dahui.,Xu Dongyan.,Qin Xiaoping.,Qin Bowen.,...&Yi Baolian.(2019).carbonsupportedultrafineptnanoparticlesmodifiedwithtraceamountsofcobaltasenhancedoxygenreductionreactioncatalystsforprotonexchangemembranefuelcells.chinesejournalofcatalysis,40(4),504.
MLA Qu Lijuan,et al."carbonsupportedultrafineptnanoparticlesmodifiedwithtraceamountsofcobaltasenhancedoxygenreductionreactioncatalystsforprotonexchangemembranefuelcells".chinesejournalofcatalysis 40.4(2019):504.
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