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题名: Selective formation of aromatic amines by selenium-catalyzed reduction of aromatic nitro compounds with CO/H2O under atmospheric pressure
作者: Liu, XZ;  Lu, SW
关键词: CO ;  reduction ;  nitro aromatic compounds ;  selenium ;  phase transfer catalysis ;  aromatic amines
刊名: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
发表日期: 2004-04-02
DOI: 10.1016/j.molcata.2003.12.004
卷: 212, 期:1-2, 页:127-130
收录类别: SCI
文章类型: Article
项目归属: 901
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: An efficient method for the catalytic reduction of aromatic nitro compounds to the corresponding aromatic amines is reported. In the presence of selenium as a catalyst, the aromatic nitro compounds are quantitively reduced by CO/H2O to form the corresponding amines under atmospheric pressure. The reduction occurs in high selectivity regardless of other reducible functionalities present on the aromatic ring. There exists a phase transfer process of the catalyst selenium in the reaction. (C) 2004 Elsevier B.V. All rights reserved.
关键词[WOS]: CARBON-MONOXIDE ;  N-HETEROCYCLIZATION ;  NITROBENZENE ;  CARBONYLATION ;  TRIETHYLAMINE ;  SOLUBILITY ;  KETONES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000220024900018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/80983
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Liaoning, Peoples R China

Recommended Citation:
Liu, XZ,Lu, SW. Selective formation of aromatic amines by selenium-catalyzed reduction of aromatic nitro compounds with CO/H2O under atmospheric pressure[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2004,212(1-2):127-130.
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