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题名: Rotamers of m-aminophenol cation studied by mass analyzed threshold ionization spectroscopy and theoretical calculations
作者: Xie, Y;  Su, HW;  Tzeng, WB
刊名: CHEMICAL PHYSICS LETTERS
发表日期: 2004-08-11
DOI: 10.1016/j.plett.2004.07.005
卷: 394, 期:1-3, 页:182-187
收录类别: SCI
文章类型: Article
项目归属: 1103
产权排名: 2;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: The vibrationally resolved spectra of selected rotamers of m-aminophenol have been recorded by mass analyzed threshold ionization spectroscopy in connection with two-color resonant two-photon excitation scheme. The adiabatic ionization energies of the cis and trans rotamers are 61460 +/- 5 and 61734 +/- 5 cm(-1), respectively. The frequencies of modes 1 (breathing) and 18a (in-plane CH bending) are measured to be 744 and 1097 cm(-1) for the cis, and 736 and 1104 cm(-1) for the trans rotamer, respectively. This indicates that different orientation of the OH with respect to the NH2 substituent only slightly influences these two modes. (C) 2004 Elsevier B.V. All rights reserved.
关键词[WOS]: POLARIZED RAMAN ;  SUPERSONIC JET ;  IR-SPECTRA ;  PHENOL ;  VIBRATIONS ;  ROTATION ;  BARRIER ;  CRYSTAL ;  ISOMERS ;  ION
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000223241800035
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/81187
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 106, Taiwan
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Xie, Y,Su, HW,Tzeng, WB. Rotamers of m-aminophenol cation studied by mass analyzed threshold ionization spectroscopy and theoretical calculations[J]. CHEMICAL PHYSICS LETTERS,2004,394(1-3):182-187.
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