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题名: Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure
作者: Xia, CH;  Xu, H;  Wu, WZ;  Liang, XM
关键词: catalytic hydrodehalogenation ;  palladium/carbon ;  aromatic halides ;  aqueous solution
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2004-08-01
DOI: 10.1016/j.catcom.2004.04.006
卷: 5, 期:8, 页:383-386
收录类别: SCI ;  CCR
文章类型: Article
项目归属: 204,1804
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The hydrodehalogenation of aromatic halides, catalyzed by Pd/C in aqueous solutions, yields arenes in short reaction times at room temperature under normal pressure. The nature of the solvents has an important influence on the reaction rates and the activity of the catalyst. The catalyst shows the highest activity in water. In the hydrodechlorination of 4-chlorohypnone, it was in water that C-Cl bond was easier to be hydrogenated, and in isopropanol that C=O was easier to be hydrogenated. (C) 2004 Elsevier B.V. All rights reserved.
关键词[WOS]: ORGANIC HALIDES ;  MILD CONDITIONS ;  RANEY-NI ;  HYDRODECHLORINATION ;  DECHLORINATION ;  HYDROGENOLYSIS ;  PT/C
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000223164100001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/82119
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Grp Pharmaceut Chem, Dalian 116012, Peoples R China

Recommended Citation:
Xia, CH,Xu, H,Wu, WZ,et al. Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure[J]. CATALYSIS COMMUNICATIONS,2004,5(8):383-386.
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