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Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure; Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure
Xia, CH; Xu, H; Wu, WZ; Liang, XM
KeywordCatalytic Hydrodehalogenation Catalytic Hydrodehalogenation Palladium/carbon Palladium/carbon Aromatic Halides Aromatic Halides Aqueous Solution Aqueous Solution
Source PublicationCATALYSIS COMMUNICATIONS ; CATALYSIS COMMUNICATIONS
2004-08-01 ; 2004-08-01
DOI10.1016/j.catcom.2004.04.006 ; 10.1016/j.catcom.2004.04.006
Volume5Issue:8Pages:383-386
Indexed BySCI ; SCI ; CCR ; CCR
SubtypeArticle ; Article
Funding Project204,1804 ; 204,1804
Contribution Rank1;1 ; 1;1
WOS HeadingsScience & Technology ; Science & Technology ; Physical Sciences ; Physical Sciences
WOS SubjectChemistry, Physical ; Chemistry, Physical
WOS Research AreaChemistry ; Chemistry
WOS KeywordORGANIC HALIDES ; ORGANIC HALIDES ; MILD CONDITIONS ; MILD CONDITIONS ; RANEY-NI ; RANEY-NI ; HYDRODECHLORINATION ; HYDRODECHLORINATION ; DECHLORINATION ; DECHLORINATION ; HYDROGENOLYSIS ; HYDROGENOLYSIS ; PT/C ; PT/C
AbstractThe hydrodehalogenation of aromatic halides, catalyzed by Pd/C in aqueous solutions, yields arenes in short reaction times at room temperature under normal pressure. The nature of the solvents has an important influence on the reaction rates and the activity of the catalyst. The catalyst shows the highest activity in water. In the hydrodechlorination of 4-chlorohypnone, it was in water that C-Cl bond was easier to be hydrogenated, and in isopropanol that C=O was easier to be hydrogenated. (C) 2004 Elsevier B.V. All rights reserved.; The hydrodehalogenation of aromatic halides, catalyzed by Pd/C in aqueous solutions, yields arenes in short reaction times at room temperature under normal pressure. The nature of the solvents has an important influence on the reaction rates and the activity of the catalyst. The catalyst shows the highest activity in water. In the hydrodechlorination of 4-chlorohypnone, it was in water that C-Cl bond was easier to be hydrogenated, and in isopropanol that C=O was easier to be hydrogenated. (C) 2004 Elsevier B.V. All rights reserved.
Language英语 ; 英语
URL查看原文 ; 查看原文
WOS IDWOS:000223164100001 ; WOS:000223164100001
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/82119
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Grp Pharmaceut Chem, Dalian 116012, Peoples R China
Recommended Citation
GB/T 7714
Xia, CH,Xu, H,Wu, WZ,et al. Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure, Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure[J]. CATALYSIS COMMUNICATIONS, CATALYSIS COMMUNICATIONS,2004, 2004,5, 5(8):383-386, 383-386.
APA Xia, CH,Xu, H,Wu, WZ,&Liang, XM.(2004).Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure.CATALYSIS COMMUNICATIONS,5(8),383-386.
MLA Xia, CH,et al."Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure".CATALYSIS COMMUNICATIONS 5.8(2004):383-386.
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