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题名: New chiral ferrocenyldiphosphine ligand for catalytic asymmetric transfer hydrogenation
作者: Dai, HC;  Hu, XP;  Chen, HL;  Bai, CM;  Zheng, Z
关键词: ferrocenyldiphosphine ;  transfer hydrogenation ;  (R)-N-(2-(diphenylphosphino)benzylidene)-1-((S)-2-(diphenylphosphino)ferrocenyl)ethylamine
刊名: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
发表日期: 2004-02-16
DOI: 10.1016/S1381-1169(03)00543-0
卷: 209, 期:1-2, 页:19-22
收录类别: SCI
文章类型: Article
项目归属: 206
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: New chiral ferrocenyldiphosphine ligands (R)-(S)-3 and (R)-(S)-4 were prepared. The ligands were employed in Ru(II) catalyzed asymmetric transfer hydrogenation of ketones to give corresponding secondary alcohols. Up to 99% conversion with 90% e.e. was obtained on Ru(DMSO)(4)Cl-2/4 in transfer hydrogenation of acetophenones with propan-2-ol. (C) 2003 Elsevier B.V. All rights reserved.
关键词[WOS]: FERROCENYLPHOSPHINE-IMINE LIGANDS ;  KETONES ;  HYDROSILYLATION
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000188208800002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/82133
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Dai, HC,Hu, XP,Chen, HL,et al. New chiral ferrocenyldiphosphine ligand for catalytic asymmetric transfer hydrogenation[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2004,209(1-2):19-22.
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