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Correlation between the characteristics and catalytic performance of Ni-V-O catalysts in oxidative dehydrogenation of propane
Bao, ZR; Li, WZ; Xu, HY; Kieffer, R
关键词Propane Oxidative Dehydrogenation Ni-v-o Catalysts
刊名CATALYSIS LETTERS
2004-04-01
94期:1-2页:125-129
收录类别SCI
文章类型Article
项目归属801
产权排名2;2
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]SB-OXIDE CATALYSTS ; IN-SITU ; OXYDEHYDROGENATION ; ETHANE ; BUTANE ; NICKEL ; REDOX
英文摘要Ni - V - O series catalysts for the oxidative dehydrogenation (ODH) of propane were prepared and characterized by BET, XRD, H-2- TPR, O-2-TPD-MS and electrical conductivity. At 425 degreesC a C3H6 selectivity of 49.9% was observed on Ni0.9V0.1OY at a C3H8 conversion of 19.4%, and the obtained selectivity is almost two times higher than that over NiO at the roughly same conversion of C3H8. The mobile oxygen species created by the interaction of NiO and V2O5 has been found in the composite catalysts by O-2-TPD-MS and electrical conductivity studies, which seems to be responsible for the enhanced selectivity of the propane oxidative dehydrogenation.
语种英语
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WOS记录号WOS:000220217400021
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/82789
专题中国科学院大连化学物理研究所
作者单位1.Inner Mongolia Normal Univ, Dept Chem, Huhehaote 010022, Inner Mongolia, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.LERCSI ECPM, F-67087 Strasbourg, France
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Bao, ZR,Li, WZ,Xu, HY,et al. Correlation between the characteristics and catalytic performance of Ni-V-O catalysts in oxidative dehydrogenation of propane[J]. CATALYSIS LETTERS,2004,94(1-2):125-129.
APA Bao, ZR,Li, WZ,Xu, HY,&Kieffer, R.(2004).Correlation between the characteristics and catalytic performance of Ni-V-O catalysts in oxidative dehydrogenation of propane.CATALYSIS LETTERS,94(1-2),125-129.
MLA Bao, ZR,et al."Correlation between the characteristics and catalytic performance of Ni-V-O catalysts in oxidative dehydrogenation of propane".CATALYSIS LETTERS 94.1-2(2004):125-129.
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