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Highly enantioselective conjugate addition of diethylzinc to acyclic enones with fine-tunable phosphite-pyridine ligands
Wan, HH; Hu, YC; Liang, YX; Gao, S; Wang, JW; Zheng, Z; Hu, XQ
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2003-10-17
DOI10.1021/jo0345897
Volume68Issue:21Pages:8277-8280
Indexed BySCI ; IC ; CCR
SubtypeArticle
Department205
Funding Project205
Contribution Rank1;1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordCHIRAL P,N LIGANDS ; CYCLIC ENONES ; ORGANOZINC REAGENTS ; PHOSPHORUS LIGANDS ; MICHAEL ADDITIONS ; ARYL DIPHOSPHITE ; PHOSPHORAMIDITES ; 1,4-ADDITION ; EFFICIENT ; COMPLEXES
AbstractA new series of fine-tunable phosphite-pyridine (P,N) ligands derived from (S)-2-amino-T-hydroxy-6,6'-dimethyl-1,1'-biphenyl and (S)-2-amino-2'-hydroxy-4,4',6,6'-tetramethyl-1,1'-biphenyl was employed in Cu(I)-catalyzed conjugate addition of diethylzinc to acyclic enones. Excellent enantioselectivities (up to 98% ee) and highly catalytic activities were achieved for a variety of acyclic enones.
Language英语
URL查看原文
WOS IDWOS:000185907100053
Citation statistics
Cited Times:43[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/82817
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Wan, HH,Hu, YC,Liang, YX,et al. Highly enantioselective conjugate addition of diethylzinc to acyclic enones with fine-tunable phosphite-pyridine ligands[J]. JOURNAL OF ORGANIC CHEMISTRY,2003,68(21):8277-8280.
APA Wan, HH.,Hu, YC.,Liang, YX.,Gao, S.,Wang, JW.,...&Hu, XQ.(2003).Highly enantioselective conjugate addition of diethylzinc to acyclic enones with fine-tunable phosphite-pyridine ligands.JOURNAL OF ORGANIC CHEMISTRY,68(21),8277-8280.
MLA Wan, HH,et al."Highly enantioselective conjugate addition of diethylzinc to acyclic enones with fine-tunable phosphite-pyridine ligands".JOURNAL OF ORGANIC CHEMISTRY 68.21(2003):8277-8280.
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