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题名: Highly enantioselective resolution of terminal epoxides with cross-linked polymeric salen-Co(III) complexes
作者: Song, YM;  Chen, HL;  Hu, XQ;  Bai, CM;  Zheng, Z
刊名: TETRAHEDRON LETTERS
发表日期: 2003-09-08
DOI: 10.1016/S0040-4039(03)01786-6
卷: 44, 期:37, 页:7081-7085
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 206
项目归属: 206
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Crosslinked polymeric salen-Co(III) complexes derived from a novel dialdehyde and a trialdehyde were synthesized and employed in the hydrolytic kinetic resolution (HKR) of terminal epoxides. Up to 99%, ee were obtained with only 0.16-0.02 mol%,, of catalyst (based on catalytic unit). (C) 2003 Elsevier Ltd. All rights reserved.
关键词[WOS]: HYDROLYTIC KINETIC RESOLUTION ;  CHIRAL CO(SALEN) COMPLEXES ;  RING-OPENING REACTIONS ;  ASYMMETRIC CATALYSIS ;  RACEMIC EPOXIDES ;  EPOXIDATION ;  OLEFINS ;  1,2-DIOLS
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000185151400025
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/82827
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Song, YM,Chen, HL,Hu, XQ,et al. Highly enantioselective resolution of terminal epoxides with cross-linked polymeric salen-Co(III) complexes[J]. TETRAHEDRON LETTERS,2003,44(37):7081-7085.
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