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题名: Reversed capillary electrochromatography: Investigation of peak symmetry for eluting curves of solutes
作者: You, HY;  Zhang, WB;  Zhang, YK
关键词: capillary electrochromatography ;  relaxation theory ;  peak symmetry
刊名: CHROMATOGRAPHIA
发表日期: 2003-09-01
DOI: 10.1365/s10337-003-0053-3
卷: 58, 期:5-6, 页:317-320
收录类别: SCI
文章类型: Article
部门归属: 1810
项目归属: 1810
产权排名: 1;1
WOS标题词: Science & Technology ;  Life Sciences & Biomedicine ;  Physical Sciences
类目[WOS]: Biochemical Research Methods ;  Chemistry, Analytical
研究领域[WOS]: Biochemistry & Molecular Biology ;  Chemistry
英文摘要: The transport processes of components in capillary electrochromatographic column was investigated based on the basic model of relaxation theory. A principal transport equation of chromatographic relaxation theory was established and mathematical expressions for eluting curves were obtained under the situations of both capillary electrophoresis and chromatography. Characteristics of peak symmetry and its effecting factors are discussed. Tailing peaks, symmetrical peaks and fronting peaks would be observed simultaneously, which was further proved with reversed capillary electrochromatographic experiments.
关键词[WOS]: ZONE ELECTROPHORESIS ;  LIQUID-CHROMATOGRAPHY ;  MATHEMATICAL-MODEL ;  SEPARATION ;  DISPERSION ;  SIMULATION ;  MIGRATION
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000185393700013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/83435
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog Res & Anal Ctr, Dalian 116011, Peoples R China

Recommended Citation:
You, HY,Zhang, WB,Zhang, YK. Reversed capillary electrochromatography: Investigation of peak symmetry for eluting curves of solutes[J]. CHROMATOGRAPHIA,2003,58(5-6):317-320.
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