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Reversed capillary electrochromatography: Investigation of peak symmetry for eluting curves of solutes
You, HY; Zhang, WB; Zhang, YK
关键词Capillary Electrochromatography Relaxation Theory Peak Symmetry
刊名CHROMATOGRAPHIA
2003-09-01
DOI10.1365/s10337-003-0053-3
58期:5-6页:317-320
收录类别SCI
文章类型Article
部门归属1810
项目归属1810
产权排名1;1
WOS标题词Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences
类目[WOS]Biochemical Research Methods ; Chemistry, Analytical
研究领域[WOS]Biochemistry & Molecular Biology ; Chemistry
关键词[WOS]ZONE ELECTROPHORESIS ; LIQUID-CHROMATOGRAPHY ; MATHEMATICAL-MODEL ; SEPARATION ; DISPERSION ; SIMULATION ; MIGRATION
英文摘要The transport processes of components in capillary electrochromatographic column was investigated based on the basic model of relaxation theory. A principal transport equation of chromatographic relaxation theory was established and mathematical expressions for eluting curves were obtained under the situations of both capillary electrophoresis and chromatography. Characteristics of peak symmetry and its effecting factors are discussed. Tailing peaks, symmetrical peaks and fronting peaks would be observed simultaneously, which was further proved with reversed capillary electrochromatographic experiments.
语种英语
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WOS记录号WOS:000185393700013
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/83435
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog Res & Anal Ctr, Dalian 116011, Peoples R China
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GB/T 7714
You, HY,Zhang, WB,Zhang, YK. Reversed capillary electrochromatography: Investigation of peak symmetry for eluting curves of solutes[J]. CHROMATOGRAPHIA,2003,58(5-6):317-320.
APA You, HY,Zhang, WB,&Zhang, YK.(2003).Reversed capillary electrochromatography: Investigation of peak symmetry for eluting curves of solutes.CHROMATOGRAPHIA,58(5-6),317-320.
MLA You, HY,et al."Reversed capillary electrochromatography: Investigation of peak symmetry for eluting curves of solutes".CHROMATOGRAPHIA 58.5-6(2003):317-320.
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