DICP OpenIR
Reversed capillary electrochromatography: Investigation of peak symmetry for eluting curves of solutes
You, HY; Zhang, WB; Zhang, YK
KeywordCapillary Electrochromatography Relaxation Theory Peak Symmetry
Source PublicationCHROMATOGRAPHIA
2003-09-01
DOI10.1365/s10337-003-0053-3
Volume58Issue:5-6Pages:317-320
Indexed BySCI
SubtypeArticle
Department1810
Funding Project1810
Contribution Rank1;1
WOS HeadingsScience & Technology ; Life Sciences & Biomedicine ; Physical Sciences
WOS SubjectBiochemical Research Methods ; Chemistry, Analytical
WOS Research AreaBiochemistry & Molecular Biology ; Chemistry
WOS KeywordZONE ELECTROPHORESIS ; LIQUID-CHROMATOGRAPHY ; MATHEMATICAL-MODEL ; SEPARATION ; DISPERSION ; SIMULATION ; MIGRATION
AbstractThe transport processes of components in capillary electrochromatographic column was investigated based on the basic model of relaxation theory. A principal transport equation of chromatographic relaxation theory was established and mathematical expressions for eluting curves were obtained under the situations of both capillary electrophoresis and chromatography. Characteristics of peak symmetry and its effecting factors are discussed. Tailing peaks, symmetrical peaks and fronting peaks would be observed simultaneously, which was further proved with reversed capillary electrochromatographic experiments.
Language英语
URL查看原文
WOS IDWOS:000185393700013
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/83435
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog Res & Anal Ctr, Dalian 116011, Peoples R China
Recommended Citation
GB/T 7714
You, HY,Zhang, WB,Zhang, YK. Reversed capillary electrochromatography: Investigation of peak symmetry for eluting curves of solutes[J]. CHROMATOGRAPHIA,2003,58(5-6):317-320.
APA You, HY,Zhang, WB,&Zhang, YK.(2003).Reversed capillary electrochromatography: Investigation of peak symmetry for eluting curves of solutes.CHROMATOGRAPHIA,58(5-6),317-320.
MLA You, HY,et al."Reversed capillary electrochromatography: Investigation of peak symmetry for eluting curves of solutes".CHROMATOGRAPHIA 58.5-6(2003):317-320.
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