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Skeletal isomerization of 1-hexene to isohexenes over zeolite catalysts
Wu, ZH; Wang, QX; Xu, LY; Xie, SJ; Aiello, R; Giordano, G; Testa, F
刊名IMPACT OF ZEOLITES AND OTHER POROUS MATERIALS ON THE NEW TECHNOLOGIES AT THE BEGINNING OF THE NEW MILLENNIUM, PTS A AND B
2002
142页:747-754
收录类别ISTP ; SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]FERRIERITE ; MECHANISM ; BUTENE
英文摘要Several zeolite catalysts such as SAPO-11, ZSM-11, ZSM-12, etc. were selected to convert I-hexene to branched hexenes in this work. Pore size of the zeolite catalyst plays an important role on the yield and the distribution of branched isohexenes. And the zeolite catalysts with the pore size of 0.6nm are optimum to produce dimethylbutenes (DMB). SAPO-11 zeolite is a suitable skeletal isomerization catalyst, especially in the production of methyl pentenes. Under the following reaction conditions: WHSV=1.0 h(-1), H-2/hexene=8, T=250 degreesC, P=0.2 MPa, the yield of skeletal isohexenes remains above 80% at the prolonged time-on stream of 80 h, accompanying low C5-, C7+ products and low carbon deposition on the catalyst.
语种英语
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WOS记录号WOS:000181696400093
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被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/83701
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Wu, ZH,Wang, QX,Xu, LY,et al. Skeletal isomerization of 1-hexene to isohexenes over zeolite catalysts[J]. IMPACT OF ZEOLITES AND OTHER POROUS MATERIALS ON THE NEW TECHNOLOGIES AT THE BEGINNING OF THE NEW MILLENNIUM, PTS A AND B,2002,142:747-754.
APA Wu, ZH.,Wang, QX.,Xu, LY.,Xie, SJ.,Aiello, R.,...&Testa, F.(2002).Skeletal isomerization of 1-hexene to isohexenes over zeolite catalysts.IMPACT OF ZEOLITES AND OTHER POROUS MATERIALS ON THE NEW TECHNOLOGIES AT THE BEGINNING OF THE NEW MILLENNIUM, PTS A AND B,142,747-754.
MLA Wu, ZH,et al."Skeletal isomerization of 1-hexene to isohexenes over zeolite catalysts".IMPACT OF ZEOLITES AND OTHER POROUS MATERIALS ON THE NEW TECHNOLOGIES AT THE BEGINNING OF THE NEW MILLENNIUM, PTS A AND B 142(2002):747-754.
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