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Selective hydrogenation of cyclopentadiene in mono- and bimetallic catalytic hollow-fiber reactors
Liu, CQ; Xu, Y; Liao, SJ; Yu, DR
关键词Catalytic Hollow-fiber Reactor Polymer-anchored Mono- And Bimetallic Catalysts Synergic Effect Selective Hydrogenation Cyclopentadiene
刊名JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
2000-06-20
157期:1-2页:253-259
收录类别SCI
文章类型Article
部门归属2
项目归属204
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]MEMBRANE REACTOR ; PALLADIUM-RUTHENIUM ; CONJUGATED DIENES ; PERVAPORATION ; OXIDATION
英文摘要The mono- and bimetallic catalytic polymeric hollow-fiber reactors were established with catalytic polymeric cellulose acetate (CA) hollow fibers prepared by supporting the polymer-anchored mono- or bimetallic catalyst in/on the inner wall of the hollow fibers. The selective hydrogenation of cyclopentadiene to cyclopentene was efficiently carried out in the above catalytic polymeric hollow-fiber reactors, especially in the NaBH4 reduced bimetallic PVP-Pd-0.5Co/CA hollow-fiber reactor under mild conditions of 40 degrees C and 0.1 MPa. It was found that there was a remarkable synergic effect of palladium and cobalt reduced by NaBH4 in the bimetallic PVP-Pd-0.5Co/CA hollow-fiber reactor, which results in a 97.5% conversion of cyclopentadiene and a 98.4% selectivity for cyclopentene. (C) 2000 Elsevier Science B.V. All rights reserved.
语种英语
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WOS记录号WOS:000087952600031
引用统计
被引频次:21[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/83933
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Liu, CQ,Xu, Y,Liao, SJ,et al. Selective hydrogenation of cyclopentadiene in mono- and bimetallic catalytic hollow-fiber reactors[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2000,157(1-2):253-259.
APA Liu, CQ,Xu, Y,Liao, SJ,&Yu, DR.(2000).Selective hydrogenation of cyclopentadiene in mono- and bimetallic catalytic hollow-fiber reactors.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,157(1-2),253-259.
MLA Liu, CQ,et al."Selective hydrogenation of cyclopentadiene in mono- and bimetallic catalytic hollow-fiber reactors".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 157.1-2(2000):253-259.
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