中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Dimerization of 1-butene via zirconium-based Ziegler-Natta catalyst
作者: Zhang, WP;  Li, C;  He, R;  Han, XW;  Bao, XH
关键词: 1-butene ;  dimerization ;  homogeneous catalysis ;  Ziegler-Natta catalyst ;  reaction mechanism
刊名: CATALYSIS LETTERS
发表日期: 2000
卷: 64, 期:2-4, 页:147-150
收录类别: SCI
文章类型: Article
部门归属: 5
项目归属: 502
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: A zirconium-based Ziegler-Natta catalytic system has been tested in the dimerization of 1-butene. It was found that the concentration of Et2AlCl, Ph3P and PhONa as well as the reaction temperature had great influences on the activity and selectivity of the catalyst. Under the optimum reaction conditions, the conversion of 1-butene is 91.9%, and the selectivity of dimers is 76.7%. Basic ligands such as Ph3P and PhONa can inhibit isomerization of 1-butene to 2-butene effectively. In addition, the metal hydride mechanism was also suggested and some indirect evidence was obtained in favor of this mechanism.
关键词[WOS]: LINEAR OLIGOMERIZATION ;  NICKEL
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000085099300013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/84229
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2000HO5NA06W2J.pdf(59KB)----开放获取--View Download

作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Sch Chem Engn, Dalian 116012, Peoples R China

Recommended Citation:
Zhang, WP,Li, C,He, R,et al. Dimerization of 1-butene via zirconium-based Ziegler-Natta catalyst[J]. CATALYSIS LETTERS,2000,64(2-4):147-150.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Zhang, WP]'s Articles
 [Li, C]'s Articles
 [He, R]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Zhang, WP]‘s Articles
 [Li, C]‘s Articles
 [He, R]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
文件名: 2000HO5NA06W2J.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace