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Oxidative dehydrogenation of ethane and propane over Mn-based catalysts
Ge, QJ; Zhaorigetu, B; Yu, CY; Li, WZ; Xu, HY
关键词Mn-based Catalysts Ethane Propane Oxidative Dehydrogenation
刊名CATALYSIS LETTERS
2000
68期:1-2页:59-62
收录类别SCI
文章类型Article
部门归属8
项目归属801
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]SELECTIVITY
英文摘要The catalytic performances of Mn-based catalysts have been investigated for the oxidative dehydrogenation of both ethane (ODE) and propane (ODP). The results show that a LiCl/MnOx/PC (Portland cement) catalyst has an excellent catalytic performance for oxidative dehydrogenation of both ethane and propane to ethylene and propylene, more than 60% alkanes conversion and more than 80% olefins selectivity could be achieved at 650 degrees C. In addition, the results indicate that Mn-based catalysts belong to p-type semiconductors, the electrical conductivity of which is the main factor in influencing the olefins selectivity. Lithium, chlorine and PC in the LiCl/MnOx/PC catalyst are all necessary components to keep the excellent catalytic performance at a low temperature.
语种英语
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WOS记录号WOS:000088361500011
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被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/84459
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Ge, QJ,Zhaorigetu, B,Yu, CY,et al. Oxidative dehydrogenation of ethane and propane over Mn-based catalysts[J]. CATALYSIS LETTERS,2000,68(1-2):59-62.
APA Ge, QJ,Zhaorigetu, B,Yu, CY,Li, WZ,&Xu, HY.(2000).Oxidative dehydrogenation of ethane and propane over Mn-based catalysts.CATALYSIS LETTERS,68(1-2),59-62.
MLA Ge, QJ,et al."Oxidative dehydrogenation of ethane and propane over Mn-based catalysts".CATALYSIS LETTERS 68.1-2(2000):59-62.
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