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题名: Oxidative carbonylation of aniline over a polymer-supported palladium-copper catalyst
作者: Wan, BS;  Liao, SJ;  Yu, DR
关键词: polymer-supported bimetallic catalyst ;  oxidative carbonylation ;  ethyl N-phenylcarbamate ;  synergic effect
刊名: REACTIVE & FUNCTIONAL POLYMERS
发表日期: 2000-08-01
卷: 45, 期:1, 页:55-59
收录类别: SCI
文章类型: Article
部门归属: 2
项目归属: 202
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Engineering, Chemical ;  Polymer Science
研究领域[WOS]: Chemistry ;  Engineering ;  Polymer Science
英文摘要: The polymer-supported bimetallic catalyst FVP-PdCl2-2CuCl(2) (PVP, poly(N-vinyl-2-pyrrolidone), obtained in situ by the addition of CuCl2 to an alcoholic solution of PVP-PdCl2, exhibits high selectivity and activity for the oxidative carbonylation of aniline with carbon monoxide and oxygen to ethyl N-phenylcarbamate in the presence of a base (NaOAc) under atmospheric pressure. The strong synergic effect of Pd-Cu gives rise to a clear increase in the selectivity and activity. (C) 2000 Elsevier Science B.V. All rights reserved.
关键词[WOS]: HOMOGENEOUS MULTIMETALLIC CATALYSTS ;  RUTHENIUM BIMETALLIC CATALYSTS ;  CARBON-MONOXIDE ;  MILD CONDITIONS ;  CARBAMATE ESTERS ;  SODIUM HYDRIDE ;  COMPLEXES ;  OLEFINS ;  HALIDES ;  AMINES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000088941500007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/84801
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wan, BS,Liao, SJ,Yu, DR. Oxidative carbonylation of aniline over a polymer-supported palladium-copper catalyst[J]. REACTIVE & FUNCTIONAL POLYMERS,2000,45(1):55-59.
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