中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Synthesis of a group of diosgenyl saponins with combined use of glycosyl trichloroacetimidate and thioglycoside donors
作者: Yu, H;  Yu, B;  Wu, XY;  Hui, YZ;  Han, XW
刊名: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
发表日期: 2000
期: 9, 页:1445-1453
收录类别: SCI ;  IC
文章类型: Article
部门归属: 5
项目归属: 502
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: With the combined use of glycosyl trichloroacetimidates and thioglycosides, a group of natural diosgenyl saponins (1-6) are efficiently synthesized, in either a stepwise or a 'one-pot' manner. The trichloroacetimidate is employed as an efficient temporary hydroxy protecting group in glycosylation with the glycosyl trichloroacetimidate. The intermolecular alkylthio-group transfer is demonstrated to be a common side-reaction during glycosylation with thioglycosides.
关键词[WOS]: INTERMOLECULAR AGLYCON TRANSFER ;  OLIGOSACCHARIDE SYNTHESIS ;  PROMOTED REACTIONS ;  ALLYL GLYCOSIDES ;  KOENIGS-KNORR ;  ONE-POT ;  POLYSACCHARIDE ;  EFFICIENT ;  NEOGLYCOPROTEINS ;  TRISACCHARIDES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000086664600022
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/85043
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2000PC2QYP00AL.pdf(858KB)----开放获取--View Download

作者单位: 1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Yu, H,Yu, B,Wu, XY,et al. Synthesis of a group of diosgenyl saponins with combined use of glycosyl trichloroacetimidate and thioglycoside donors[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1,2000(9):1445-1453.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Yu, H]'s Articles
 [Yu, B]'s Articles
 [Wu, XY]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Yu, H]‘s Articles
 [Yu, B]‘s Articles
 [Wu, XY]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
文件名: 2000PC2QYP00AL.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace