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Photodissociation of o-dichlorobenzene at 266 nm
Zhu, RS; Zhang, H; Wang, GJ; Gu, XB; Han, KL; He, GZ; Lou, NQ
刊名CHEMICAL PHYSICS
1999-10-01
248期:2-3页:285-292
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]EXCITED-STATES ; ALKYL-HALIDES ; 193 NM ; CHLOROBENZENE ; FRAGMENT
英文摘要The photodissociation o-dichlorobenzene at 266 nm has been investigated using the universal crossed molecular beam technique. Photofragment translational energy distribution P(E-t) and angular distribution of photofragments have been obtained and it is estimated that 23% of the available energy is assigned to translational energy. The anisotropy parameter is determined to be 0.4. From P(E-t) and beta we deduce that o-C6H4Cl2 photodissociation is a slow process. Ab initio calculation has been performed and it shows that the parent molecule has a larger geometry deformation in its excited states comparing with that of the ground state. The possible dissociation mechanism has also been proposed. (C) 1999 Elsevier Science B.V. All rights reserved.
语种英语
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WOS记录号WOS:000083954300012
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被引频次:29[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/85293
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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GB/T 7714
Zhu, RS,Zhang, H,Wang, GJ,et al. Photodissociation of o-dichlorobenzene at 266 nm[J]. CHEMICAL PHYSICS,1999,248(2-3):285-292.
APA Zhu, RS.,Zhang, H.,Wang, GJ.,Gu, XB.,Han, KL.,...&Lou, NQ.(1999).Photodissociation of o-dichlorobenzene at 266 nm.CHEMICAL PHYSICS,248(2-3),285-292.
MLA Zhu, RS,et al."Photodissociation of o-dichlorobenzene at 266 nm".CHEMICAL PHYSICS 248.2-3(1999):285-292.
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