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题名: Epoxidation of styrene with NaOCl and catalyzed by nickel(II) complexes
作者: Yin, GC;  Xi, ZW;  Cao, GY
关键词: nickel(II) complexes ;  catalytic epoxidation ;  styrene ;  NaOCl
刊名: OXIDATION COMMUNICATIONS
发表日期: 1999
卷: 22, 期:1, 页:54-61
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Epoxidation of styrene was catalyzed by some nickel(II) complexes, with NaOCl as the oxygen donor. The catalyst Ni(PA)(2). 2H(2)O has been found to be stable for the epoxidation of styrene. Some additives were introduced in the reaction to improve the "micro-environment" of the catalyst. Radical trap had little influence on styrene epoxidation. It was interesting to find that phase-transfer agent had negative influence on epoxidation in this biphase reaction. A possible mechanism of styrene epoxidation catalyzed by Ni(PA)(2). 2H(2)O has been proposed.
关键词[WOS]: OLEFINS ;  HYDROPEROXIDES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000079730600006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/85495
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Yin, GC,Xi, ZW,Cao, GY. Epoxidation of styrene with NaOCl and catalyzed by nickel(II) complexes[J]. OXIDATION COMMUNICATIONS,1999,22(1):54-61.
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