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题名: Ferrocenylphosphine-imine ligands for Pd-catalyzed asymmetric allylic alkylation
作者: Hu, XP;  Dai, HG;  Hu, XU;  Chen, HL;  Wang, JW;  Bai, CM;  Zheng, Z
刊名: TETRAHEDRON-ASYMMETRY
发表日期: 2002-08-14
卷: 13, 期:15, 页:1687-1693
收录类别: IC ;  CCR ;  SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Ferrocenylphosphine-imine ligands 6 derived front (R,S)-PPFNH2-R 5 and a variety of benzaldehydes were applied in the Pd-catalyzed asymmetric allylic alkylation of 1,3-diphenylprop-2-en-1-yl acetate 7a or pivalate 7b with dimethyl malonate. The substituent effects on the catalytic reaction were investigated, and 96% e.e. with 99% yield was achieved when the m-nitro substituted ligand 6k was used. (C) 2002 Elsevier Science Ltd. All rights reserved.
关键词[WOS]: TRANSITION-METAL-COMPLEXES ;  CHIRAL FERROCENYLPHOSPHINES ;  AMINOPHOSPHINE LIGANDS ;  NITROGEN SUBSTITUENTS ;  PLANAR CHIRALITY ;  HECK REACTION ;  N LIGANDS ;  ALLYLATION ;  SUBSTITUTIONS ;  P,N-LIGANDS
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000178048300015
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/85523
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Hu, XP,Dai, HG,Hu, XU,et al. Ferrocenylphosphine-imine ligands for Pd-catalyzed asymmetric allylic alkylation[J]. TETRAHEDRON-ASYMMETRY,2002,13(15):1687-1693.
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