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Polymer-supported palladium-manganese bimetallic catalyst for the oxidative carbonylation of amines to carbamate esters
Wan, BS; Liao, SJ; Yu, DR
关键词Polymer-supported Bimetallic Catalyst Synergic Effect Oxidative Carbonylation Carbamate Esters
刊名APPLIED CATALYSIS A-GENERAL
1999-07-05
183期:1页:81-84
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Life Sciences & Biomedicine
类目[WOS]Chemistry, Physical ; Environmental Sciences
研究领域[WOS]Chemistry ; Environmental Sciences & Ecology
关键词[WOS]HOMOGENEOUS MULTIMETALLIC CATALYSTS ; CARBON-MONOXIDE ; MILD CONDITIONS ; SODIUM HYDRIDE ; RUTHENIUM ; HYDROFORMYLATION ; HYDROGENATION ; OLEFINS ; ANILINE ; HALIDES
英文摘要The polymer-supported bimetallic catalyst PVP-PdCl2-MnCl2 (PVP=poly(N-vinyl-2-pyrrolidone)) exhibits high activity and selectivity for the oxidative carbonylation of amines with carbon monoxide and oxygen to carbamate esters under atmospheric pressure in the presence of a base (NaOAc). This catalyst is prepared by the addition of MnCl2 to the alcoholic solution of PVP-PdCl2 in situ. A remarkable bimetallic synergic effect and the role of PVP in PVP-PdCl2-MXn (MXn=the second transition metal component such as NiCl2, CoCl2, MnCl2 and FeCl3) gives rise to an obvious increase in the conversion and selectivity for the reaction. Among the second metal components tested, Mn-Pd exerts the strongest synergic effect. (C) 1999 Elsevier Science B.V. All rights reserved.
语种英语
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WOS记录号WOS:000080489400008
引用统计
被引频次:53[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/86099
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Wan, BS,Liao, SJ,Yu, DR. Polymer-supported palladium-manganese bimetallic catalyst for the oxidative carbonylation of amines to carbamate esters[J]. APPLIED CATALYSIS A-GENERAL,1999,183(1):81-84.
APA Wan, BS,Liao, SJ,&Yu, DR.(1999).Polymer-supported palladium-manganese bimetallic catalyst for the oxidative carbonylation of amines to carbamate esters.APPLIED CATALYSIS A-GENERAL,183(1),81-84.
MLA Wan, BS,et al."Polymer-supported palladium-manganese bimetallic catalyst for the oxidative carbonylation of amines to carbamate esters".APPLIED CATALYSIS A-GENERAL 183.1(1999):81-84.
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