中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Polymer-supported palladium-manganese bimetallic catalyst for the oxidative carbonylation of amines to carbamate esters
作者: Wan, BS;  Liao, SJ;  Yu, DR
关键词: polymer-supported bimetallic catalyst ;  synergic effect ;  oxidative carbonylation ;  carbamate esters
刊名: APPLIED CATALYSIS A-GENERAL
发表日期: 1999-07-05
卷: 183, 期:1, 页:81-84
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Physical ;  Environmental Sciences
研究领域[WOS]: Chemistry ;  Environmental Sciences & Ecology
英文摘要: The polymer-supported bimetallic catalyst PVP-PdCl2-MnCl2 (PVP=poly(N-vinyl-2-pyrrolidone)) exhibits high activity and selectivity for the oxidative carbonylation of amines with carbon monoxide and oxygen to carbamate esters under atmospheric pressure in the presence of a base (NaOAc). This catalyst is prepared by the addition of MnCl2 to the alcoholic solution of PVP-PdCl2 in situ. A remarkable bimetallic synergic effect and the role of PVP in PVP-PdCl2-MXn (MXn=the second transition metal component such as NiCl2, CoCl2, MnCl2 and FeCl3) gives rise to an obvious increase in the conversion and selectivity for the reaction. Among the second metal components tested, Mn-Pd exerts the strongest synergic effect. (C) 1999 Elsevier Science B.V. All rights reserved.
关键词[WOS]: HOMOGENEOUS MULTIMETALLIC CATALYSTS ;  CARBON-MONOXIDE ;  MILD CONDITIONS ;  SODIUM HYDRIDE ;  RUTHENIUM ;  HYDROFORMYLATION ;  HYDROGENATION ;  OLEFINS ;  ANILINE ;  HALIDES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000080489400008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/86099
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
199947C26EI387.pdf(106KB)----开放获取--View Download

作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wan, BS,Liao, SJ,Yu, DR. Polymer-supported palladium-manganese bimetallic catalyst for the oxidative carbonylation of amines to carbamate esters[J]. APPLIED CATALYSIS A-GENERAL,1999,183(1):81-84.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Wan, BS]'s Articles
 [Liao, SJ]'s Articles
 [Yu, DR]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Wan, BS]‘s Articles
 [Liao, SJ]‘s Articles
 [Yu, DR]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
文件名: 199947C26EI387.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace