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A remarkable synergic effect of water-soluble bimetallic catalyst in the hydrogenation of aromatic nitrocompounds
Jiang, H; Xu, Y; Liao, SJ; Yu, DR; Chen, H; Li, XJ
KeywordWater-soluble Bimetallic Catalysts Synergic Effect Hydrogenation Aromatic Nitrocompounds
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
1999-06-10
Volume142Issue:2Pages:147-152
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordHOMOGENEOUS MULTIMETALLIC CATALYSTS ; SELECTIVE HYDROGENATION ; AQUEOUS-SOLUTIONS ; NITRO-COMPOUNDS ; RUTHENIUM ; COMPLEXES ; CLUSTERS ; RHODIUM ; HYDROFORMYLATION ; SPECTROSCOPY
AbstractHydrogenation of nitrobenzene can be catalyzed by the water-soluble catalyst PdCl2(TPPTS)(2) (TPPTS = tris(m-sulfonatophenyl)phosphine trisodium salt) under normal pressure at 65 degrees C in H2O/toluene biphasic solvent system. The exhibits higher catalytic activity and selectivity for the hydrogenation of aromatic nitrocompounds, compared with PdCl2(TPPTS)(2) or H2PtCl6 alone. The transmission electron micrographs demonstrate that the monometallic catalyst is composed of ultrafine palladium particles of almost uniform size while the particles of bimetallic catalyst are more widely distributed in size than those of the monometallic ones. (C) 1999 Elsevier Science B.V. All rights reserved.
Language英语
URL查看原文
WOS IDWOS:000079815100005
Citation statistics
Cited Times:28[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/86135
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Sichuan Univ, Dept Chem, Chengdu 610064, Peoples R China
Recommended Citation
GB/T 7714
Jiang, H,Xu, Y,Liao, SJ,et al. A remarkable synergic effect of water-soluble bimetallic catalyst in the hydrogenation of aromatic nitrocompounds[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,142(2):147-152.
APA Jiang, H,Xu, Y,Liao, SJ,Yu, DR,Chen, H,&Li, XJ.(1999).A remarkable synergic effect of water-soluble bimetallic catalyst in the hydrogenation of aromatic nitrocompounds.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,142(2),147-152.
MLA Jiang, H,et al."A remarkable synergic effect of water-soluble bimetallic catalyst in the hydrogenation of aromatic nitrocompounds".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 142.2(1999):147-152.
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