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题名: Selective oxidation of m-phenoxytoluene to m-phenoxybenzaldehyde with methanol as an additive in acetic acid
作者: Yin, GC;  Xi, ZW;  Cao, GY;  Fan, SH;  Hai, XD
关键词: acetic acid/methanol solvents ;  m-phenoxytoluene ;  m-phenoxybenzaldehyde ;  oxidation ;  cobalt bromide catalyst
刊名: APPLIED CATALYSIS A-GENERAL
发表日期: 1999-09-20
卷: 185, 期:2, 页:277-281
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Physical ;  Environmental Sciences
研究领域[WOS]: Chemistry ;  Environmental Sciences & Ecology
英文摘要: With addition of methanol in acetic acid solvent, m-phenoxytoluene could be oxidized to m-phenoxybenzaldehyde selectively by a cobalt bromide catalyst. Paratemters such as the ratio of Co/Br and the reaction time of m-phenoxytoluene oxidation as well as visible spectra of cobalt bromide in acetic acid/methanol solvents, were also investigated. Addition of methanol caused the oxidation of aldehydes to proceed more slowly than it did solely in acetic acid solvent. The decrease of cobaltous-multibromides in acetic acid/methanol solvents was responsible for the improvement in the selective oxidation of m-phenoxytoluene. (C) 1999 Elsevier Science B.V. All rights reserved.
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000081999800013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/86139
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Yin, GC,Xi, ZW,Cao, GY,et al. Selective oxidation of m-phenoxytoluene to m-phenoxybenzaldehyde with methanol as an additive in acetic acid[J]. APPLIED CATALYSIS A-GENERAL,1999,185(2):277-281.
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