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High performance cocktail functional monomer for making molecule imprinting polymer; High performance cocktail functional monomer for making molecule imprinting polymer
Meng, ZH; Wang, JF; Zhou, LM; Wang, QH; Zhu, DQ
关键词Molecule Imprinting Molecule Imprinting Enantiomer Separation Enantiomer Separation Chiral Stationary Phase Chiral Stationary Phase Amino Acid Amino Acid
刊名ANALYTICAL SCIENCES ; ANALYTICAL SCIENCES
1999-02-01 ; 1999-02-01
15期:2页:141-144
收录类别SCI ; SCI
文章类型Article ; Article
WOS标题词Science & Technology ; Science & Technology ; Physical Sciences ; Physical Sciences
类目[WOS]Chemistry, Analytical ; Chemistry, Analytical
研究领域[WOS]Chemistry ; Chemistry
关键词[WOS]CHIRAL STATIONARY-PHASE ; CHIRAL STATIONARY-PHASE ; RESOLUTION ; RESOLUTION
英文摘要In order to make a molecule imprinting polymer (MIP) with highly chiral selectivity against N-t-Boc-L-Trp, a new kind of "cocktail" functional monomer: acrylamide+2-vinylpyridine was investigated. The MIP showed impressive chiral selectivity (alpha=3.23). With the increasing of water content in the mobile phase, ionic and hydrophobic interaction were found to be responsible for the chiral recognition process instead of the hydrogen bond. Tailing and peak asymmetry problems were overcome by using linear gradient elution. Physical properties such as thermal stability and pore structure for the MIP were also investigated.; In order to make a molecule imprinting polymer (MIP) with highly chiral selectivity against N-t-Boc-L-Trp, a new kind of "cocktail" functional monomer: acrylamide+2-vinylpyridine was investigated. The MIP showed impressive chiral selectivity (alpha=3.23). With the increasing of water content in the mobile phase, ionic and hydrophobic interaction were found to be responsible for the chiral recognition process instead of the hydrogen bond. Tailing and peak asymmetry problems were overcome by using linear gradient elution. Physical properties such as thermal stability and pore structure for the MIP were also investigated.
语种英语 ; 英语
原文出处查看原文 ; 查看原文
WOS记录号WOS:000078551300006 ; WOS:000078551300006
引用统计
被引频次:22[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/86809
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem & Phys, Dalian 116012, Peoples R China
推荐引用方式
GB/T 7714
Meng, ZH,Wang, JF,Zhou, LM,et al. High performance cocktail functional monomer for making molecule imprinting polymer, High performance cocktail functional monomer for making molecule imprinting polymer[J]. ANALYTICAL SCIENCES, ANALYTICAL SCIENCES,1999, 1999,15, 15(2):141-144, 141-144.
APA Meng, ZH,Wang, JF,Zhou, LM,Wang, QH,&Zhu, DQ.(1999).High performance cocktail functional monomer for making molecule imprinting polymer.ANALYTICAL SCIENCES,15(2),141-144.
MLA Meng, ZH,et al."High performance cocktail functional monomer for making molecule imprinting polymer".ANALYTICAL SCIENCES 15.2(1999):141-144.
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