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题名: High performance cocktail functional monomer for making molecule imprinting polymer
作者: Meng, ZH;  Wang, JF;  Zhou, LM;  Wang, QH;  Zhu, DQ
关键词: molecule imprinting ;  enantiomer separation ;  chiral stationary phase ;  amino acid
刊名: ANALYTICAL SCIENCES
发表日期: 1999-02-01
卷: 15, 期:2, 页:141-144
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical
研究领域[WOS]: Chemistry
英文摘要: In order to make a molecule imprinting polymer (MIP) with highly chiral selectivity against N-t-Boc-L-Trp, a new kind of "cocktail" functional monomer: acrylamide+2-vinylpyridine was investigated. The MIP showed impressive chiral selectivity (alpha=3.23). With the increasing of water content in the mobile phase, ionic and hydrophobic interaction were found to be responsible for the chiral recognition process instead of the hydrogen bond. Tailing and peak asymmetry problems were overcome by using linear gradient elution. Physical properties such as thermal stability and pore structure for the MIP were also investigated.
关键词[WOS]: CHIRAL STATIONARY-PHASE ;  RESOLUTION
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000078551300006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/86809
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem & Phys, Dalian 116012, Peoples R China

Recommended Citation:
Meng, ZH,Wang, JF,Zhou, LM,et al. High performance cocktail functional monomer for making molecule imprinting polymer[J]. ANALYTICAL SCIENCES,1999,15(2):141-144.
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