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题名: First example of asymmetric transfer hydrogenation in water induced by a chiral amino alcohol hydrochloride
作者: Mao, JC;  Wan, BS;  Wu, F;  Lu, SW
通讯作者: 万伯顺
关键词: n
刊名: TETRAHEDRON LETTERS
发表日期: 2005-10-24
DOI: 10.1016/j.tetlet.2005.08.129
卷: 46, 期:43, 页:7341-7344
收录类别: SCI ;  CCR
文章类型: Article
部门归属: 2,9
项目归属: 202,901
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The low-cost and commercially available (-)-ephedrine hydrochloride was firstly employed in the [RuCl2(1)-cymene)](2)-catalyzed asymmetric transfer hydrogenation of prochiral ketones in water. The reaction could be performed in the open air at rt, affording excellent yields (up to 99%) and good enantioselectivities (up to 83% ee). It provided a further step toward the discovery of simplified catalyst systems for eventual availability. (c) 2005 Published by Elsevier Ltd.
关键词[WOS]: ENANTIOSELECTIVE TRANSFER HYDROGENATION ;  SOLUBLE AMINOSULFONAMIDE LIGANDS ;  AROMATIC KETONES ;  FINE CHEMICALS ;  AQUEOUS-MEDIA ;  CATALYZED HYDROGENATION ;  RUTHENIUM(II) COMPLEXES ;  BIPHASIC CATALYSIS ;  CARBONYL-COMPOUNDS ;  TRANSFER REDUCTION
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000232437400013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/92529
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Mao, JC,Wan, BS,Wu, F,et al. First example of asymmetric transfer hydrogenation in water induced by a chiral amino alcohol hydrochloride[J]. TETRAHEDRON LETTERS,2005,46(43):7341-7344.
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