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题名: Highly efficient route to diselenides from the reactions of imines and selenium in the presence of carbon monoxide and water
作者: Zhao, XD;  Yu, ZK;  Zeng, FL;  Chen, JZ;  Wu, XW;  Wu, SZ;  Xiao, WJ;  Zheng, ZY
通讯作者: 余正坤
关键词: carbon monoxide ;  diselenation ;  diselenides ;  imines ;  selenium
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2005-05-01
DOI: 10.1002/adsc.200404380
卷: 347, 期:6, 页:877-882
收录类别: SCI ;  IC
文章类型: Article
部门归属: 2
项目归属: 203
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Applied ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Reactions of selenium with imines ((RRC)-C-1=NR2) of aldehydes and ketones in the presence of carbon monoxide, water and triethylamine lead to reductive selenation, on aerobic work-up, to afford symmetrical diselenides ((RRCHSe)-C-1)(2) in good to excellent yields. The proposed mechanism suggests that both in situ generated carbonyl selenide (SeCO) and hydrogen selenide (H2Se) are involved in the reaction.
关键词[WOS]: UNSYMMETRICAL DIORGANYL SELENIDES ;  FUNCTIONALIZED DISELENIDES ;  CHEMOSELECTIVE SYNTHESIS ;  SYMMETRICAL DISELENIDES ;  AROMATIC-ALDEHYDES ;  ALKYL-HALIDES ;  SELENOCYSTEINE DERIVATIVES ;  REDUCTIVE SELENATION ;  CONVENIENT SYNTHESIS ;  ORGANIC DISELENIDES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000229345400021
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/92547
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China

Recommended Citation:
Zhao, XD,Yu, ZK,Zeng, FL,et al. Highly efficient route to diselenides from the reactions of imines and selenium in the presence of carbon monoxide and water[J]. ADVANCED SYNTHESIS & CATALYSIS,2005,347(6):877-882.
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