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Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions
Wu, WH; Xu, J; Ohnishi, R; Xu J(徐杰); Xu J(徐杰)
KeywordHydrodechlorination Substituted Chlorobenzenes Polychlorinated Benzenes Nickel Carbon Substituent Effect
Source PublicationAPPLIED CATALYSIS B-ENVIRONMENTAL
2005-09-01
DOI10.1016/j.apcatb.2005.03.003
Volume60Issue:1-2Pages:129-137
Indexed BySCI
SubtypeArticle
Department2
Funding Project204
Contribution Rank1;1
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Engineering, Environmental ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordNOBLE-METAL CATALYSTS ; MILD CONDITIONS ; CHLORINATED BENZENES ; SURFACE-STRUCTURE ; HYDRODEHALOGENATION ; CARBON ; 1,2,4-TRICHLOROBENZENE ; PALLADIUM ; HALIDES ; HYDROGENOLYSIS
AbstractLiquid phase hydrodechlorination of chlorobenzene was studied over Ni/active carbon (Ni/AC), Ni/gamma-Al2O3, Ni/SiO2 and Raney Ni. The complete hydrodechlorination of chlorobenzene was realized at 333-343 K on Ni/AC under hydrogen atmosphere of 1.0 MPa in the presence of alkaline hydroxide. Aryl halides, three chlorotoluenes (o-, m- and p-), three chloroanilines, three chlorobenzotrifluorides, three dichlorobenzenes and two trichlorobenzenes (1,2,3- and 1,2,4-) were also completely hydrodechlorinated under the similar conditions. Chlorobenzene derivatives having either an electron-donating group or an electron-withdrawing group decreased their reactivities with respect to the unsubstituted chlorobenzene.
Language英语
URL查看原文
WOS IDWOS:000232328900014
Citation statistics
Cited Times:55[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/92581
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu J(徐杰); Xu J(徐杰)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Japan Sci & Technol Agcy, Kawaguchi 3320012, Japan
Recommended Citation
GB/T 7714
Wu, WH,Xu, J,Ohnishi, R,et al. Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2005,60(1-2):129-137.
APA Wu, WH,Xu, J,Ohnishi, R,徐杰,&徐杰.(2005).Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions.APPLIED CATALYSIS B-ENVIRONMENTAL,60(1-2),129-137.
MLA Wu, WH,et al."Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions".APPLIED CATALYSIS B-ENVIRONMENTAL 60.1-2(2005):129-137.
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