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题名: Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions
作者: Wu, WH;  Xu, J;  Ohnishi, R
通讯作者: 徐杰
关键词: hydrodechlorination ;  substituted chlorobenzenes ;  polychlorinated benzenes ;  nickel carbon ;  substituent effect
刊名: APPLIED CATALYSIS B-ENVIRONMENTAL
发表日期: 2005-09-01
DOI: 10.1016/j.apcatb.2005.03.003
卷: 60, 期:1-2, 页:129-137
收录类别: SCI
文章类型: Article
部门归属: 2
项目归属: 204
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Physical ;  Engineering, Environmental ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: Liquid phase hydrodechlorination of chlorobenzene was studied over Ni/active carbon (Ni/AC), Ni/gamma-Al2O3, Ni/SiO2 and Raney Ni. The complete hydrodechlorination of chlorobenzene was realized at 333-343 K on Ni/AC under hydrogen atmosphere of 1.0 MPa in the presence of alkaline hydroxide. Aryl halides, three chlorotoluenes (o-, m- and p-), three chloroanilines, three chlorobenzotrifluorides, three dichlorobenzenes and two trichlorobenzenes (1,2,3- and 1,2,4-) were also completely hydrodechlorinated under the similar conditions. Chlorobenzene derivatives having either an electron-donating group or an electron-withdrawing group decreased their reactivities with respect to the unsubstituted chlorobenzene.
关键词[WOS]: NOBLE-METAL CATALYSTS ;  MILD CONDITIONS ;  CHLORINATED BENZENES ;  SURFACE-STRUCTURE ;  HYDRODEHALOGENATION ;  CARBON ;  1,2,4-TRICHLOROBENZENE ;  PALLADIUM ;  HALIDES ;  HYDROGENOLYSIS
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000232328900014
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/92581
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Japan Sci & Technol Agcy, Kawaguchi 3320012, Japan

Recommended Citation:
Wu, WH,Xu, J,Ohnishi, R. Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2005,60(1-2):129-137.
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