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Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions
Wu, WH; Xu, J; Ohnishi, R; Xu J(徐杰); Xu J(徐杰)
关键词Hydrodechlorination Substituted Chlorobenzenes Polychlorinated Benzenes Nickel Carbon Substituent Effect
刊名APPLIED CATALYSIS B-ENVIRONMENTAL
2005-09-01
DOI10.1016/j.apcatb.2005.03.003
60期:1-2页:129-137
收录类别SCI
文章类型Article
部门归属2
项目归属204
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Engineering, Environmental ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]NOBLE-METAL CATALYSTS ; MILD CONDITIONS ; CHLORINATED BENZENES ; SURFACE-STRUCTURE ; HYDRODEHALOGENATION ; CARBON ; 1,2,4-TRICHLOROBENZENE ; PALLADIUM ; HALIDES ; HYDROGENOLYSIS
英文摘要Liquid phase hydrodechlorination of chlorobenzene was studied over Ni/active carbon (Ni/AC), Ni/gamma-Al2O3, Ni/SiO2 and Raney Ni. The complete hydrodechlorination of chlorobenzene was realized at 333-343 K on Ni/AC under hydrogen atmosphere of 1.0 MPa in the presence of alkaline hydroxide. Aryl halides, three chlorotoluenes (o-, m- and p-), three chloroanilines, three chlorobenzotrifluorides, three dichlorobenzenes and two trichlorobenzenes (1,2,3- and 1,2,4-) were also completely hydrodechlorinated under the similar conditions. Chlorobenzene derivatives having either an electron-donating group or an electron-withdrawing group decreased their reactivities with respect to the unsubstituted chlorobenzene.
语种英语
原文出处查看原文
WOS记录号WOS:000232328900014
引用统计
被引频次:54[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/92581
专题中国科学院大连化学物理研究所
通讯作者Xu J(徐杰); Xu J(徐杰)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Japan Sci & Technol Agcy, Kawaguchi 3320012, Japan
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Wu, WH,Xu, J,Ohnishi, R,et al. Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2005,60(1-2):129-137.
APA Wu, WH,Xu, J,Ohnishi, R,徐杰,&徐杰.(2005).Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions.APPLIED CATALYSIS B-ENVIRONMENTAL,60(1-2),129-137.
MLA Wu, WH,et al."Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions".APPLIED CATALYSIS B-ENVIRONMENTAL 60.1-2(2005):129-137.
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