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Reversal of predominant enantioselectivity in the asymmetric alkynylation reaction using sulfamide-amine alcohols
Mao, Jincheng; Zhang, Zhanjin; Wan, Boshun; Wu, Fan; Lu, Shiwei; Wan BS(万伯顺); Wan BS(万伯顺)
关键词Reversal Of Stereochemistry Enantioselective Alkynylzinc Addition L-proline Propargylic Alcohols Aldehydes
刊名CATALYSIS COMMUNICATIONS
2006-08-01
DOI10.1016/j.catcom.2006.01.015
7期:8页:550-553
收录类别SCI ; IC ; CCR
文章类型Article
部门归属2,9
项目归属202,901
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]AROMATIC-ALDEHYDES ; PHENYLACETYLENE ADDITION ; DIETHYLZINC ; LIGANDS ; ALKYNYLZINC ; CATALYSTS ; KETONES ; BINOL
英文摘要The change of substituent in the backbone Of L-proline-derived sulfamide-amine alcohol ligand 3 provides chiral propargylic alcohols with the opposite configurations in significant enantioselectivities in the asymmetric addition of phenylacetylene to aldehydes. Meanwhile, the ligand 3 in combination with Ti((OPr)-Pr-i)(4) could also afford the products with opposite absolute configuration in high yields. (c) 2006 Elsevier B.V. All rights reserved.
语种英语
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WOS记录号WOS:000238799500008
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/97239
专题中国科学院大连化学物理研究所
通讯作者Wan BS(万伯顺); Wan BS(万伯顺)
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Grp 202, Dalian 116023, Peoples R China
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GB/T 7714
Mao, Jincheng,Zhang, Zhanjin,Wan, Boshun,et al. Reversal of predominant enantioselectivity in the asymmetric alkynylation reaction using sulfamide-amine alcohols[J]. CATALYSIS COMMUNICATIONS,2006,7(8):550-553.
APA Mao, Jincheng.,Zhang, Zhanjin.,Wan, Boshun.,Wu, Fan.,Lu, Shiwei.,...&万伯顺.(2006).Reversal of predominant enantioselectivity in the asymmetric alkynylation reaction using sulfamide-amine alcohols.CATALYSIS COMMUNICATIONS,7(8),550-553.
MLA Mao, Jincheng,et al."Reversal of predominant enantioselectivity in the asymmetric alkynylation reaction using sulfamide-amine alcohols".CATALYSIS COMMUNICATIONS 7.8(2006):550-553.
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