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题名: Observing the stereodynamics of chemical reactions using randomly oriented molecular beams
作者: Gustafsson, M;  Skodje, RT;  Zhang, JY;  Dai, DX;  Harich, SA;  Wang, XY;  Yang, XM
通讯作者: Rex T.Skodje ;  杨学明
刊名: JOURNAL OF CHEMICAL PHYSICS
发表日期: 2006-06-28
DOI: 10.1063/1.2217015
卷: 124, 期:24, 页:241105-1-241105-4
收录类别: SCI
文章类型: Article
部门归属: 11
项目归属: 1102
产权排名: 2;3
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: A new method is demonstrated to study the stereodynamics of simple chemical reactions that does not require the use of oriented (or aligned) molecular beams or measurements of the orientation state of product molecules. Instead, it is shown that by numerically combining accurate measurements of the state-to-state differential cross section for two or more rotational states of the reagent molecule, the separate contribution from the individual helicity states can be extracted. New molecular beam experiments are conducted for the D+H-2 -> HD+H reaction that confirm the validity of the method. (c) 2006 American Institute of Physics.
关键词[WOS]: REACTION DYNAMICS ;  TRANSITION-STATES ;  SCATTERING ;  STEREOCHEMISTRY ;  REACTIVITY
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000238730600005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/97259
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan
2.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Gustafsson, M,Skodje, RT,Zhang, JY,et al. Observing the stereodynamics of chemical reactions using randomly oriented molecular beams[J]. JOURNAL OF CHEMICAL PHYSICS,2006,124(24):241105-1-241105-4.
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