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题名: New efficient organocatalytic oxidation of benzylic compounds by molecular oxygen under mild conditions
作者: Tong, XL;  Xu, J;  Miao, H;  Gao, J
通讯作者: 徐杰
关键词: benzylic oxidation ;  organocatalysis ;  molecular oxygen ;  acridine yellow
刊名: TETRAHEDRON LETTERS
发表日期: 2006-03-13
DOI: 10.1016/j.tetlet.2006.01.028
卷: 47, 期:11, 页:1763-1766
收录类别: SCI ;  CCR
文章类型: Article
部门归属: 2
项目归属: 204
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Efficient aerobic oxidation of benzylic Compounds has been achieved under no irradiation using a new organocatalytic system in the presence of acridine yellow and N-hydroxyphthalimide with assistance of a catalytic amount of molecular bromine. Various substrates, especially alkylaromatics, were effectively oxygenated to the corresponding carbonyl Compounds with molecular oxygen as oxidant under mild conditions. For instance, indan was oxidized with 92% conversion and 79% selectivity for I-indanone under 0.3 MPa Of O-2 at 75 degrees C. (c) 2006 Elsevier Ltd. All rights reserved.
关键词[WOS]: N-HYDROXYPHTHALIMIDE NHPI ;  PHOTOINDUCED ELECTRON-TRANSFER ;  CATALYTIC-SYSTEM ;  SELECTIVE OXYGENATION ;  AROMATIC-COMPOUNDS ;  HYDROGEN-PEROXIDE ;  AEROBIC OXIDATION ;  METAL-FREE ;  ALKYLBENZENES ;  ALCOHOLS
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000235647300018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/97849
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Grad Sch, Dalian 116023, Peoples R China

Recommended Citation:
Tong, XL,Xu, J,Miao, H,et al. New efficient organocatalytic oxidation of benzylic compounds by molecular oxygen under mild conditions[J]. TETRAHEDRON LETTERS,2006,47(11):1763-1766.
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