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New efficient organocatalytic oxidation of benzylic compounds by molecular oxygen under mild conditions
Tong, XL; Xu, J; Miao, H; Gao, J; Xu J(徐杰); Xu J(徐杰)
关键词Benzylic Oxidation Organocatalysis Molecular Oxygen Acridine Yellow
刊名TETRAHEDRON LETTERS
2006-03-13
DOI10.1016/j.tetlet.2006.01.028
47期:11页:1763-1766
收录类别SCI ; CCR
文章类型Article
部门归属2
项目归属204
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]N-HYDROXYPHTHALIMIDE NHPI ; PHOTOINDUCED ELECTRON-TRANSFER ; CATALYTIC-SYSTEM ; SELECTIVE OXYGENATION ; AROMATIC-COMPOUNDS ; HYDROGEN-PEROXIDE ; AEROBIC OXIDATION ; METAL-FREE ; ALKYLBENZENES ; ALCOHOLS
英文摘要Efficient aerobic oxidation of benzylic Compounds has been achieved under no irradiation using a new organocatalytic system in the presence of acridine yellow and N-hydroxyphthalimide with assistance of a catalytic amount of molecular bromine. Various substrates, especially alkylaromatics, were effectively oxygenated to the corresponding carbonyl Compounds with molecular oxygen as oxidant under mild conditions. For instance, indan was oxidized with 92% conversion and 79% selectivity for I-indanone under 0.3 MPa Of O-2 at 75 degrees C. (c) 2006 Elsevier Ltd. All rights reserved.
语种英语
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WOS记录号WOS:000235647300018
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被引频次:24[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/97849
专题中国科学院大连化学物理研究所
通讯作者Xu J(徐杰); Xu J(徐杰)
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Grad Sch, Dalian 116023, Peoples R China
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GB/T 7714
Tong, XL,Xu, J,Miao, H,et al. New efficient organocatalytic oxidation of benzylic compounds by molecular oxygen under mild conditions[J]. TETRAHEDRON LETTERS,2006,47(11):1763-1766.
APA Tong, XL,Xu, J,Miao, H,Gao, J,徐杰,&徐杰.(2006).New efficient organocatalytic oxidation of benzylic compounds by molecular oxygen under mild conditions.TETRAHEDRON LETTERS,47(11),1763-1766.
MLA Tong, XL,et al."New efficient organocatalytic oxidation of benzylic compounds by molecular oxygen under mild conditions".TETRAHEDRON LETTERS 47.11(2006):1763-1766.
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