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题名: Readily available phosphine-phosphoramidite ligands for highly efficient Rh-catalyzed enantioselective hydrogenations
作者: Huang, Jia-Di;  Hu, Xiang-Ping;  Duan, Zheng-Chao;  Zeng, Qing-Hen;  Yu, Sai-Bo;  Deng, Jun;  Wang, Dao-Yong;  Zheng, Zhuo
通讯作者: 郑卓
刊名: ORGANIC LETTERS
发表日期: 2006-09-14
DOI: 10.1021/ol0617749
卷: 8, 期:19, 页:4367-4370
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 206
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A new family of air- and moisture-stable phosphine-phosphoramidite ligands (PEAPhos) has been prepared from commercially available and inexpensive ( S)-alpha-phenylethylamine through a two- or three-step transformation and successfully applied in the rhodium-catalyzed enantioselective hydrogenations of a variety of substrates, in which up to 99.9% ee was obtained for all of these kinds of substrates.
关键词[WOS]: PHENYLETHYLAMINE ALPHA-PEA ;  ASYMMETRIC HYDROGENATION ;  ENANTIOPURE COMPOUNDS ;  FERROCENYL LIGANDS ;  PHOSPHORUS LIGANDS ;  ACID-DERIVATIVES ;  COMPLEXES ;  QUINAPHOS
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000240339700049
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/98095
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Huang, Jia-Di,Hu, Xiang-Ping,Duan, Zheng-Chao,et al. Readily available phosphine-phosphoramidite ligands for highly efficient Rh-catalyzed enantioselective hydrogenations[J]. ORGANIC LETTERS,2006,8(19):4367-4370.
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