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题名: UV Raman spectroscopic study on TiO2. I. Phase transformation at the surface and in the bulk
作者: Zhang, J;  Li, MJ;  Feng, ZC;  Chen, J;  Li, C
通讯作者: 李灿
刊名: JOURNAL OF PHYSICAL CHEMISTRY B
发表日期: 2006-01-19
DOI: 10.1021/jp0552473
卷: 110, 期:2, 页:927-935
收录类别: SCI
文章类型: Article
部门归属: 5
项目归属: 503
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Phase transformation of TiO2 from anatase to rutile is studied by UV Raman spectroscopy excited by 325 and 244 nm lasers, visible Rainan spectroscopy excited by 532 nm laser, X-ray diffraction (XRD), and transmission electron microscopy (TEM). UV Raman spectroscopy is found to be more sensitive to the surface region of TiO2 than visible Raman spectroscopy and XRD because TiO2 strongly absorbs UV light. The anatase phase is detected by UV Raman spectroscopy for the sample calcined at higher temperatures than when it is detected by visible Raman spectroscopy and XRD. The inconsistency in the results from the above three techniques suggests that the anatase phase of TiO2 at the surface region can remain at relatively higher calcination temperatures than that in the bulk during the phase transformation. The TEM results show that small particles agglomerate into big particles when the TiO2 sample is calcined at elevated temperatures and the agglomeration of the TiO2 particles is along with the phase transformation from anatase to rutile. It is suggested that the rutile phase starts to form at the interfaces between the anatase particles in the agglomerated TiO2 particles; namely, the anatase phase in the inner region of the agglomerated TiO2 particles turns out to change into the rutile phase more easily than that in the outer surface region of the agglomerated TiO2 particles. When the anatase particles of TiO2 are covered with highly dispersed La2O3, the phase transformation in both the bulk and surface regions is significantly retarded, owing to avoiding direct contact of the anatase particles and occupying the surface defect sites of the anatase particles by La2O3.
关键词[WOS]: ANATASE-TO-RUTILE ;  NANOCRYSTALLINE TITANIA ;  PHOTOCATALYTIC ACTIVITY ;  GRAIN-GROWTH ;  POWDERS ;  WATER ;  KINETICS ;  CALCINATION ;  EVOLUTION ;  DIOXIDE
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000234699200046
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/98231
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Zhang, J,Li, MJ,Feng, ZC,et al. UV Raman spectroscopic study on TiO2. I. Phase transformation at the surface and in the bulk[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2006,110(2):927-935.
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