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题名: Rh(II) carbene S-H insertion into H2S via the stepwise mechanism
作者: Liu, Zhen Feng;  Yue, Xian Fang;  Wei, Qiang;  Han, Ke Li
通讯作者: 韩克利
关键词: sulfonium ylides ;  1,2-hydrogen shift ;  density functional calculations ;  dirhodium(II) carbene
刊名: CHINESE CHEMICAL LETTERS
发表日期: 2007
DOI: 10.1016/j.cclet.2006.11.012
卷: 18, 期:1, 页:107-110
收录类别: SCI
文章类型: Article
部门归属: 11
项目归属: 1101
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The mechanism of Rh(H) carbene S-H insertion into H2S in gas phase has been studied by B3LYP functional. Calculation results showed that the Rh(II) carbene S-H insertion into H2S took only stepwise channels and no concerted channels had been located, which was different from the Rh(H) carbene C-H and O-H insertions. (c) 2006 Ke Li Han. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
关键词[WOS]: DIAZO COMPOUND ;  TETRACARBOXYLATE ;  CYCLOPROPENATION ;  ALDEHYDES ;  DENSITY ;  ALKYNES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000244443600033
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/98533
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Liu, Zhen Feng,Yue, Xian Fang,Wei, Qiang,et al. Rh(II) carbene S-H insertion into H2S via the stepwise mechanism[J]. CHINESE CHEMICAL LETTERS,2007,18(1):107-110.
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