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题名: Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate
作者: Zhang, Shengjun;  Gao, Shuang;  Xi, Zuwei;  Xu, Jie
通讯作者: 高爽
关键词: alcohol ;  oxidation ;  solvent-free ;  hydrogen peroxide ;  heteropolyphosphatotungstate
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2007-03-01
DOI: 10.1016/j.catcom.2006.02.020
卷: 8, 期:3, 页:531-534
收录类别: SCI ;  CCR
文章类型: Article
部门归属: 2
项目归属: 208
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: With aqueous hydrogen peroxide as oxidant, secondary alcohols could be efficiently oxidized to ketones in the presence of hexadecyl trimethyl ammonium heteropolyphosphatotungstate ((n-C16H33N(CH3)(3))(3)[PW4O16]) under solvent-free conditions. The oxidation of alcohol over 0.5 mol% (based on molar amount of hydrogen peroxide) catalyst occurred at 90 degrees C to give the corresponding ketones with above 92% yield and 97% selectivity. The catalyst could be reused without loss of selectivity. (c) 2006 Elsevier B.V. All rights reserved.
关键词[WOS]: AQUEOUS HYDROGEN-PEROXIDE ;  ATOM ECONOMY ;  KETONES ;  EPOXIDATION ;  OXIDE
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000243163000062
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/98657
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Zhang, Shengjun,Gao, Shuang,Xi, Zuwei,et al. Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate[J]. CATALYSIS COMMUNICATIONS,2007,8(3):531-534.
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