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Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate
Zhang, Shengjun; Gao, Shuang; Xi, Zuwei; Xu, Jie; Gao S(高爽); Gao S(高爽)
关键词Alcohol Oxidation Solvent-free Hydrogen Peroxide Heteropolyphosphatotungstate
刊名CATALYSIS COMMUNICATIONS
2007-03-01
DOI10.1016/j.catcom.2006.02.020
8期:3页:531-534
收录类别SCI ; CCR
文章类型Article
部门归属2
项目归属208
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]AQUEOUS HYDROGEN-PEROXIDE ; ATOM ECONOMY ; KETONES ; EPOXIDATION ; OXIDE
英文摘要With aqueous hydrogen peroxide as oxidant, secondary alcohols could be efficiently oxidized to ketones in the presence of hexadecyl trimethyl ammonium heteropolyphosphatotungstate ((n-C16H33N(CH3)(3))(3)[PW4O16]) under solvent-free conditions. The oxidation of alcohol over 0.5 mol% (based on molar amount of hydrogen peroxide) catalyst occurred at 90 degrees C to give the corresponding ketones with above 92% yield and 97% selectivity. The catalyst could be reused without loss of selectivity. (c) 2006 Elsevier B.V. All rights reserved.
语种英语
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WOS记录号WOS:000243163000062
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被引频次:32[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/98657
专题中国科学院大连化学物理研究所
通讯作者Gao S(高爽); Gao S(高爽)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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GB/T 7714
Zhang, Shengjun,Gao, Shuang,Xi, Zuwei,et al. Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate[J]. CATALYSIS COMMUNICATIONS,2007,8(3):531-534.
APA Zhang, Shengjun,Gao, Shuang,Xi, Zuwei,Xu, Jie,高爽,&高爽.(2007).Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate.CATALYSIS COMMUNICATIONS,8(3),531-534.
MLA Zhang, Shengjun,et al."Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate".CATALYSIS COMMUNICATIONS 8.3(2007):531-534.
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