DICP OpenIR
Hydrogen production from steam reforming of ethanol and glycerol over ceria-supported metal catalysts
Zhang, Baocai; Tang, Xiaolan; Li, Yong; Xu, Yide; Shen, Wenjie; Shen WJ(申文杰); Shen WJ(申文杰)
关键词Hydrogen Production Ethanol Glycerol Steam Reforming M/ceo2 Catalysts
刊名INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
2007-09-01
DOI10.1016/j.ijhydene.2006.11.003
32期:13页:2367-2373
收录类别SCI
文章类型Article
部门归属5
项目归属501
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Electrochemistry ; Energy & Fuels
研究领域[WOS]Chemistry ; Electrochemistry ; Energy & Fuels
关键词[WOS]HYDROCARBONS ; MECHANISM ; INSIGHTS ; H-2 ; RH ; CE
英文摘要Hydrogen production from the steam reforming reactions of ethanol and glycerol has been studied over ceria-supported Ir, Co and Ni catalysts with respect to the nature of the active metals and the reaction pathways. For ethanol steam reforming, ethanol dehydrogenation to acetaldehyde and ethanol decomposition to methane and carbon monoxide were the primary reactions at low temperatures, depending on the active metals. At higher temperatures where all the ethanol and the intermediate compounds, like acetaldehyde and acetone, were completely converted into hydrogen, carbon oxides and methane, steam reforming of methane and water gas shift became the major reactions. The Ir/CeO2 catalyst was significantly more active and selective toward hydrogen production, and the superior catalytic performance was interpreted in terms of the intimated contact between Ir particles and ceria based on the ceria-mediated redox process. Additionally, hydrogen production from steam reforming of glycerol was also examined over these ceria-supported metal catalysts, and the lr/CeO2 catalyst again showed quite promising catalytic performance with hydrogen selectivity of more than 85% and 100% glycerol conversion at 400 degrees C. (C) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
语种英语
原文出处查看原文
WOS记录号WOS:000250062900032
引用统计
被引频次:288[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/98735
专题中国科学院大连化学物理研究所
通讯作者Shen WJ(申文杰); Shen WJ(申文杰)
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Baocai,Tang, Xiaolan,Li, Yong,et al. Hydrogen production from steam reforming of ethanol and glycerol over ceria-supported metal catalysts[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2007,32(13):2367-2373.
APA Zhang, Baocai.,Tang, Xiaolan.,Li, Yong.,Xu, Yide.,Shen, Wenjie.,...&申文杰.(2007).Hydrogen production from steam reforming of ethanol and glycerol over ceria-supported metal catalysts.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,32(13),2367-2373.
MLA Zhang, Baocai,et al."Hydrogen production from steam reforming of ethanol and glycerol over ceria-supported metal catalysts".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 32.13(2007):2367-2373.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zhang, Baocai]的文章
[Tang, Xiaolan]的文章
[Li, Yong]的文章
百度学术
百度学术中相似的文章
[Zhang, Baocai]的文章
[Tang, Xiaolan]的文章
[Li, Yong]的文章
必应学术
必应学术中相似的文章
[Zhang, Baocai]的文章
[Tang, Xiaolan]的文章
[Li, Yong]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。