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题名: Selective oxidation of ethylbenzene by a biomimetic combination: Hemin and N-hydroxyphthalimide (NHPI)
作者: Ma, Hong;  Xu, Jie;  Zhang, Qiaohong;  Miao, Hong;  Wu, Wenhai
通讯作者: 徐杰
关键词: ethylbenzene ;  hemin ;  N-hydroxyphthalimide ;  oxidation
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2007
DOI: 10.1016/j.catcom.2006.05.023
卷: 8, 期:1, 页:27-30
收录类别: SCI ;  CCR
文章类型: Article
部门归属: 2
项目归属: 204
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: A biomimetic catalytic system consisting of hemin and N-hydroxyphthalimide (NHPI) for the selective oxidation of ethylbenzene with dioxygen is reported. 90.32% conversion of ethylbenzene with 94.30% selectivity for acetophenone (AcPO) can be obtained at 100 degrees C under 0.3 MPa O-2 for 9 h. Hemin can efficiently decompose in situ formed 1-phenylethyl hydroperoxide (PEHP) with AcPO as the main product. (c) 2006 Elsevier B.V. All rights reserved.
关键词[WOS]: MOLECULAR-OXYGEN ;  IRON-PORPHYRINS ;  SYSTEM ;  METALLOPORPHYRINS ;  HYDROPEROXIDES ;  HYDROCARBONS ;  CYCLOHEXANE ;  EPOXIDATION ;  MECHANISM ;  CLEAVAGE
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000242759500006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/98931
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Grad Sch, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Ma, Hong,Xu, Jie,Zhang, Qiaohong,et al. Selective oxidation of ethylbenzene by a biomimetic combination: Hemin and N-hydroxyphthalimide (NHPI)[J]. CATALYSIS COMMUNICATIONS,2007,8(1):27-30.
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