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A remarkable promoting effect of water addition on selective hydrogenation of p-chloronitrobenzene in ethanol
Ning, Jianbo; Xu, Jie; Liu, Jing; Miao, Hong; Ma, Hong; Chen, Chen; Li, Xiaoqlang; Zhou, Lipeng; Yu, Weiqiang; Xu J(徐杰); Xu J(徐杰)
关键词P-chloronitrobenzene (P-cnb) P-chloraniline (P-can) Hydrogenation Ethanol Water
刊名CATALYSIS COMMUNICATIONS
2007-11-01
DOI10.1016/j.catcom.2007.01.032
8期:11页:1763-1766
收录类别SCI ; CCR
文章类型Article
部门归属2
项目归属204
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]LIQUID-PHASE HYDROGENATION ; RUTHENIUM COLLOIDAL CATALYSTS ; SUPPORTED PLATINUM CATALYSTS ; TRANSITION-METAL CR ; O-CHLORONITROBENZENE ; NI ; FE ; CYCLOHEXENE ; BENZENE ; MN
英文摘要Selective hydrogenation of p-chloronitrobenzene to p-chloraniline over ruthenium catalyst was found to be promoted remarkably (Selectivity: from 80.4% to 98.6%; TON: from 0.89 x 10(-2) s(-1) to 3.20 x 10(-2) s(-1)) by simply adding some water into the solvent of ethanol. The optimized volume percent of water in ethanol was 30%. The promoting effect of water was also found over various supported metal catalysts, such as Fe/SiO2, CO/SiO2, Ni/SiO2, CU/SiO2, and Ag/SiO2. (c) 2007 Elsevier B.V. All rights reserved.
语种英语
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WOS记录号WOS:000250256700040
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被引频次:51[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/98939
专题中国科学院大连化学物理研究所
通讯作者Xu J(徐杰); Xu J(徐杰)
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Grad Sch, State Key Lab Catalysis, Dalian 116023, Peoples R China
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GB/T 7714
Ning, Jianbo,Xu, Jie,Liu, Jing,et al. A remarkable promoting effect of water addition on selective hydrogenation of p-chloronitrobenzene in ethanol[J]. CATALYSIS COMMUNICATIONS,2007,8(11):1763-1766.
APA Ning, Jianbo.,Xu, Jie.,Liu, Jing.,Miao, Hong.,Ma, Hong.,...&徐杰.(2007).A remarkable promoting effect of water addition on selective hydrogenation of p-chloronitrobenzene in ethanol.CATALYSIS COMMUNICATIONS,8(11),1763-1766.
MLA Ning, Jianbo,et al."A remarkable promoting effect of water addition on selective hydrogenation of p-chloronitrobenzene in ethanol".CATALYSIS COMMUNICATIONS 8.11(2007):1763-1766.
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