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题名: A remarkable promoting effect of water addition on selective hydrogenation of p-chloronitrobenzene in ethanol
作者: Ning, Jianbo;  Xu, Jie;  Liu, Jing;  Miao, Hong;  Ma, Hong;  Chen, Chen;  Li, Xiaoqlang;  Zhou, Lipeng;  Yu, Weiqiang
通讯作者: 徐杰
关键词: p-chloronitrobenzene (p-CNB) ;  p-chloraniline (p-CAN) ;  hydrogenation ;  ethanol ;  water
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2007-11-01
DOI: 10.1016/j.catcom.2007.01.032
卷: 8, 期:11, 页:1763-1766
收录类别: SCI ;  CCR
文章类型: Article
部门归属: 2
项目归属: 204
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Selective hydrogenation of p-chloronitrobenzene to p-chloraniline over ruthenium catalyst was found to be promoted remarkably (Selectivity: from 80.4% to 98.6%; TON: from 0.89 x 10(-2) s(-1) to 3.20 x 10(-2) s(-1)) by simply adding some water into the solvent of ethanol. The optimized volume percent of water in ethanol was 30%. The promoting effect of water was also found over various supported metal catalysts, such as Fe/SiO2, CO/SiO2, Ni/SiO2, CU/SiO2, and Ag/SiO2. (c) 2007 Elsevier B.V. All rights reserved.
关键词[WOS]: LIQUID-PHASE HYDROGENATION ;  RUTHENIUM COLLOIDAL CATALYSTS ;  SUPPORTED PLATINUM CATALYSTS ;  TRANSITION-METAL CR ;  O-CHLORONITROBENZENE ;  NI ;  FE ;  CYCLOHEXENE ;  BENZENE ;  MN
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000250256700040
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/98939
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Grad Sch, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Ning, Jianbo,Xu, Jie,Liu, Jing,et al. A remarkable promoting effect of water addition on selective hydrogenation of p-chloronitrobenzene in ethanol[J]. CATALYSIS COMMUNICATIONS,2007,8(11):1763-1766.
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