DICP OpenIR
AN environmentally benign route for epichlorohydrin from allyl chloride epoxidation catalyzed by heteropolyphosphatotungstate
Li, Jian; Xi, Zuwei; Gao, Shuang; Xi ZW(奚祖威)
关键词Allyl Chloride Epoxidation Heteropolyphosphatotungstate Hydrogen Peroxide
刊名RESEARCH ON CHEMICAL INTERMEDIATES
2007
33期:6页:523-534
收录类别SCI ; CCR
文章类型Review
部门归属2
项目归属208
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]HYDROGEN-PEROXIDE ; MOLECULAR-OXYGEN ; OLEFINS
英文摘要In the absence of organic solvent, allyl chloride was epoxidized with aqueous hydrogen peroxide catalyzed by a heteropolyphosphatotungstate catalyst with very good activity and recycling activity. Under optimized conditions, an epichlorohydrin yield of 88.7% was achieved in the first run; after two recycles, the epichlorohydrin yield remained still above 85.0%. Various factors affecting the catalytic reaction were investigated systematically. The reaction rate of hydrogen peroxide in the epoxidation of allyl chloride is zero order with respect to hydrogen peroxide. The activation energy is 52.27 kJ/mol.
语种英语
原文出处查看原文
WOS记录号WOS:000250112200005
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/98945
专题中国科学院大连化学物理研究所
通讯作者Xi ZW(奚祖威)
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Li, Jian,Xi, Zuwei,Gao, Shuang,et al. AN environmentally benign route for epichlorohydrin from allyl chloride epoxidation catalyzed by heteropolyphosphatotungstate[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2007,33(6):523-534.
APA Li, Jian,Xi, Zuwei,Gao, Shuang,&奚祖威.(2007).AN environmentally benign route for epichlorohydrin from allyl chloride epoxidation catalyzed by heteropolyphosphatotungstate.RESEARCH ON CHEMICAL INTERMEDIATES,33(6),523-534.
MLA Li, Jian,et al."AN environmentally benign route for epichlorohydrin from allyl chloride epoxidation catalyzed by heteropolyphosphatotungstate".RESEARCH ON CHEMICAL INTERMEDIATES 33.6(2007):523-534.
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