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Hydrogen generation utilizing alkaline sodium borohydride solution and supported cobalt catalyst
Ye, Wei; Zhang, Huamin; Xu, Dongyan; Ma, Li; Yi, Baolian; Zhang HM(张华民); Zhang HM(张华民)
关键词Hydrogen Generation Sodium Borohydride Supported Co Catalyst Hydrolysis
刊名JOURNAL OF POWER SOURCES
2007-02-10
DOI10.1016/j.jpowsour.2006.09.114
164期:2页:544-548
收录类别SCI
文章类型Article
部门归属3
项目归属303
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Electrochemistry ; Energy & Fuels
研究领域[WOS]Electrochemistry ; Energy & Fuels
关键词[WOS]MEMBRANE FUEL-CELLS ; HIGH-PERFORMANCE ; NABH4 SOLUTION ; RU CATALYST ; HYDROLYSIS ; HYDRIDES
英文摘要Supported Co catalysts with different supports were prepared for hydrogen generation (HG) from catalytic hydrolysis of alkaline sodium borohydride solution. As a result, we found that a gamma-Al2O3 supported Co catalyst was very effective because of its special structure. A maximum HG rate of 220 mL min(-1) g(-1) catalyst and approximately 100% efficiency at 303 K were achieved using a Co/gamma-Al2O3 catalyst containing 9 wt.% Co. The catalyst has quick response and good durability to the hydrolysis of alkaline NaBH4 Solution. It is feasible to use this catalyst in hydrogen generators with stabilized NaBH4 solutions to provide on-site hydrogen with desired rate for mobile applications, such as proton exchange membrane fuel cell (PEMFC) systems. (c) 2006 Elsevier B.V. All rights reserved.
语种英语
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WOS记录号WOS:000244359500016
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被引频次:162[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/98983
专题中国科学院大连化学物理研究所
通讯作者Zhang HM(张华民); Zhang HM(张华民)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab PEMFC Key Mat & Technol, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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Ye, Wei,Zhang, Huamin,Xu, Dongyan,et al. Hydrogen generation utilizing alkaline sodium borohydride solution and supported cobalt catalyst[J]. JOURNAL OF POWER SOURCES,2007,164(2):544-548.
APA Ye, Wei.,Zhang, Huamin.,Xu, Dongyan.,Ma, Li.,Yi, Baolian.,...&张华民.(2007).Hydrogen generation utilizing alkaline sodium borohydride solution and supported cobalt catalyst.JOURNAL OF POWER SOURCES,164(2),544-548.
MLA Ye, Wei,et al."Hydrogen generation utilizing alkaline sodium borohydride solution and supported cobalt catalyst".JOURNAL OF POWER SOURCES 164.2(2007):544-548.
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