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题名: A novel way to chiral 2-oxazolidinones: selenium-catalyzed cyclocarbonylation of 2-aminoethanols
作者: Li, Peng1, 2;  Yuan, Xiaohua1;  Wang, Shudong1;  Lu, Shiwei1
通讯作者: 陆世维
关键词: chiral 2-oxazolidinones ;  2-aminoethanols ;  carbon monoxide ;  selenium
刊名: TETRAHEDRON
发表日期: 2007-12-10
DOI: 10.1016/j.tet.2007.09.037
卷: 63, 期:50, 页:12419-12423
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 9
项目归属: 901
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Selenium-catalyzed cyclocarbonylation of 2-aminoethanols with CO under atmospheric pressure at 30 degrees C afforded 2-oxazolidinones in excellent yields without any other co-catalyst. The method was then applied to the syntheses of chiral 2-oxazolidinones and no racemization was detected. (c) 2007 Elsevier Ltd. All rights reserved.
关键词[WOS]: BETA-AMINO ALCOHOLS ;  OXIDATIVE CARBONYLATION ;  ASYMMETRIC-SYNTHESIS ;  CARBON-MONOXIDE ;  REACTION PROVIDES ;  FACILE SYNTHESIS ;  OXAZOLIDIN-2-ONES ;  PALLADIUM ;  OXAZOLIDINONES ;  DERIVATIVES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000252218600017
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/99433
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Li, Peng,Yuan, Xiaohua,Wang, Shudong,et al. A novel way to chiral 2-oxazolidinones: selenium-catalyzed cyclocarbonylation of 2-aminoethanols[J]. TETRAHEDRON,2007,63(50):12419-12423.
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