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题名: Selective hydrogenation of acetonitrile over molybdenum phosphide catalysts
作者: Yang, Pengfei;  Jiang, Zongxuan;  Ying, Pinliang;  Li, Can
通讯作者: 李灿
关键词: transition metal phosphide ;  molybdenum ;  acetonitrile ;  selective hydrogenation ;  ethylamine
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2007-08-01
卷: 28, 期:8, 页:670-672
收录类别: SCI
文章类型: Article
部门归属: 5
项目归属: 503
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: A series of molybdenum phosphide catalysts were prepared at initial Mo/P molar ratios ranging from 0.6 to 2.6. The catalytic activity of the catalysts for the selective hydrogenation of acetonitrile was studied. The catalysts with initial Mo/P ratios>1.0 have high selectivity forethylamine (80% -90%), and for the catalysts with Mo/P ratios < 1. 0, the selectivity for diethylamine and triethylamine is more favorable (about 90% When Mo/P ratio= 1.0, the highest conversion of acetonitrile is attained.
关键词[WOS]: PHASE HYDROGENATION ;  LIQUID-PHASE
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000249472100002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/99665
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Yang, Pengfei,Jiang, Zongxuan,Ying, Pinliang,et al. Selective hydrogenation of acetonitrile over molybdenum phosphide catalysts[J]. CHINESE JOURNAL OF CATALYSIS,2007,28(8):670-672.
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