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题名: Thermodynamic properties of the binary mixture of water and n-butanol
作者: Nan, Z.;  Tan, Z-C.
通讯作者: 南照东
关键词: adiabatic calorimetry ;  heat capacity ;  low temperature ;  n-butanol ;  water
刊名: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
发表日期: 2007
DOI: 10.1007/s10973-005-7295-2
卷: 87, 期:2, 页:539-544
收录类别: SCI
文章类型: Article
部门归属: 15
项目归属: 1504
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The molar heat capacities of the binary mixture composed of water and n-butanol were measured with an adiabatic calorimeter in the temperature range 78-320 K. The functions of the heat capacity with respect to thermodynamic temperature were established. A glass transition, solid-solid phase transition and solid-liquid phase transition were observed. The corresponding enthalpy and entropy of the solid-liquid phase transition were calculated, respectively. The thermodynamic functions relative to a temperature of 298.15 K were derived based on the relationships of the thermodynamic functions and the function of the measured heat capacity with respect to temperature.
关键词[WOS]: HEAT-CAPACITIES ;  THERMAL-ANALYSIS ;  ACID
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000244313900041
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/99735
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Qufu Normal Univ, Dept Chem, Shandong 273165, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China

Recommended Citation:
Nan, Z.,Tan, Z-C.. Thermodynamic properties of the binary mixture of water and n-butanol[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2007,87(2):539-544.
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